(C) A standard sclution of hydratcd iron(11) sulphate, FeSO,.XH20, was preparcd by dissolving 5.8 g of the salt in a volumetric flask and making it up to 250 mL (250 cm³). Twenty-five millilitres (25 mL (25 cm³)) of this solution was acidified and found to react exactly with, 22.8 cm³ (22.8 mL), of 0.018 M potassium permanganate solution. The half-equations for the reaction are: MnO, (aq) + 8H*(aq) Fe"(aq)- + Mn²*(aq) + 4H2O(1) → Fe"(aq) + e YATIM (i) What is the indicator for the titration of a solution of iron (II) sulphate and potassium permanganate solution? berio (ii) Indicate the colour at the end point if the permanganate is in the burette. . (iii) Why is it necessary to acidify the iron(II) solution before titration?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter13: Titrations In Analytical Chemistry
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Problem 13.12QAP
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(5) A standard sclution of hydrated iron(II) sulphate, FeSO,.XH20, was preparcd by dissolving 5.8 g of the
salt in a volumetric flask and making it up to 250 mL (250 cm³). Twenty-five millilitres (25 mL (25 cm³)) of
this solution was acidified and found to react exactly with, 22.8 cm³ (22.8 mL), of 0.018 M potassium
3
permanganate solution. The half-equations for the reaction are:
JAS 00
MAC
aJTT
MNO4 (aq) + 8H*(aq)
Fe*(aq)
+ Mn2“(aq) + 4H20(1)
→ Fe*(aq) + e
MOTTAMIMAXE
2+
(i; What is the indicator for the titration of a solution of iron (II) sulphate and potassium permanganate soluticn?
(ii) Indicate the colour at the end point if the permanganate is in the burette.
blood
ofieido rosd sl
(iii) Why is it necessary to acidify the iron(II) solution before titration?
o sd am eorsiuols
Transcribed Image Text:(5) A standard sclution of hydrated iron(II) sulphate, FeSO,.XH20, was preparcd by dissolving 5.8 g of the salt in a volumetric flask and making it up to 250 mL (250 cm³). Twenty-five millilitres (25 mL (25 cm³)) of this solution was acidified and found to react exactly with, 22.8 cm³ (22.8 mL), of 0.018 M potassium 3 permanganate solution. The half-equations for the reaction are: JAS 00 MAC aJTT MNO4 (aq) + 8H*(aq) Fe*(aq) + Mn2“(aq) + 4H20(1) → Fe*(aq) + e MOTTAMIMAXE 2+ (i; What is the indicator for the titration of a solution of iron (II) sulphate and potassium permanganate soluticn? (ii) Indicate the colour at the end point if the permanganate is in the burette. blood ofieido rosd sl (iii) Why is it necessary to acidify the iron(II) solution before titration? o sd am eorsiuols
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