Calculate the activation energy of a reaction if its rate constant is 2.8 x 10® s-1 at 24°C and 1.5 x 107 s-1 at 48°C.

Chemistry for Engineering Students
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Chapter10: Entropy And The Second Law Of Thermodynamics
Section: Chapter Questions
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k2 = 11.5 s-1 at T2 = 75°C + 273
R= 8.314 J/mol•K
Required
Ea
Strategy:
Use Arrhenius
equation:
k
In
In 0.75 s1 =
En
348.15 K
298.15 K
11.5 s-1
8.314 J/mol-K
(- 0.000481691 K-1)
En
8.314 J/mol•K
-2.73003 =
- 2.73003
E =
- 0.000057937
J/mol
E, = 47.1 kJ/mol
reck
Activity 4
Problem Solving: Copy the problem below and answer. Write your answer in a separate sheet of
рaper.
Calculate the activation energy of a reaction if its rate constant is 2.8 x 106 s-1 at 24°C and 1.5 x 107
s-1 at 48°C.
5. Overview (STEM- GC11CKIli-j-138)
A catalyst is a substance that changes the speed of a chemical reaction without undergoing a
permanent chemical change itself. Most reactions in the body, the atmosphere, and the oceans occur
with the help of catalysts. Much industrial chemical research is devoted to the search for more effective
catalysts for reactions of commercial importance.
A. Homogeneous catalyst
A catalyst that is present in the same phase as the reactants in a reaction mixture is called a
homogeneous catalyst. Examples abound both in solution and in the gas phase. Consider, for
example, the decomposition of aqueous hydrogen peroxide, H2O2(aq), into water and oxygen:
2 H2O2(aq) 2 H2O(1) + O2(g)
2 Br (aq) + H2O2{aq) + 2 H*Br2(aq) + 2 H20(1) (with catalyst as Br (aq)) same
(without catalyst)
phase with H2O2{aq)
Transcribed Image Text:k2 = 11.5 s-1 at T2 = 75°C + 273 R= 8.314 J/mol•K Required Ea Strategy: Use Arrhenius equation: k In In 0.75 s1 = En 348.15 K 298.15 K 11.5 s-1 8.314 J/mol-K (- 0.000481691 K-1) En 8.314 J/mol•K -2.73003 = - 2.73003 E = - 0.000057937 J/mol E, = 47.1 kJ/mol reck Activity 4 Problem Solving: Copy the problem below and answer. Write your answer in a separate sheet of рaper. Calculate the activation energy of a reaction if its rate constant is 2.8 x 106 s-1 at 24°C and 1.5 x 107 s-1 at 48°C. 5. Overview (STEM- GC11CKIli-j-138) A catalyst is a substance that changes the speed of a chemical reaction without undergoing a permanent chemical change itself. Most reactions in the body, the atmosphere, and the oceans occur with the help of catalysts. Much industrial chemical research is devoted to the search for more effective catalysts for reactions of commercial importance. A. Homogeneous catalyst A catalyst that is present in the same phase as the reactants in a reaction mixture is called a homogeneous catalyst. Examples abound both in solution and in the gas phase. Consider, for example, the decomposition of aqueous hydrogen peroxide, H2O2(aq), into water and oxygen: 2 H2O2(aq) 2 H2O(1) + O2(g) 2 Br (aq) + H2O2{aq) + 2 H*Br2(aq) + 2 H20(1) (with catalyst as Br (aq)) same (without catalyst) phase with H2O2{aq)
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