
World of Chemistry
7th Edition
ISBN: 9780618562763
Author: Steven S. Zumdahl
Publisher: Houghton Mifflin College Div
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Calculate the heat change in kilojoules for freezing 30.0 g of water at 0 ∘C.
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The enthalpy of vaporization of water is larger than its enthalpy of fusion. Explain why.
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Sodium chloride is added in cooking to enhance the flavor of food. When 10.00 g of NaCl are dissolved in 200.0 mL of water at 25.0C in a coffee-cup calorimeter, 669 J of heat are absorbed. (You can make the following assumptions about the solution: volume =200.0 mL, density =1.00 g/mL, specific heat =4.18J/gC) (a) Is the solution process exothermic? (b) What is qH2O? (c) What is the final temperature of the solution?
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If 14.5 kJ of heat were added to 485 g of liquid water, how much would its temperature increase?
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If you want to convert 56.0 g ice (at 0 °C) to water at 75.0 °C, calculate how many grams of propane, C3H8, you would have to bum to supply the energy to melt the ice and then warm it to the final temperature (at 1 bar).
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Which requires the absorption of a greater amount of heat—vaporizing 100.0 g of benzene or boiling 20.0 g of water? (Use Table 8.2.)
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Why does sweating cool the human body?
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Are changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar heat of fusion and molar heat of vaporization. Why is the molar heat of vaporization of water so much larger than its molar heat of fusion? Why does the boiling point of a liquid vary with altitude?
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Will a closed container of water at 70 C or an open container of water at the same temperature cool faster on a cold winter day? Explain why.
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1. Which of the following processes requires the largest input of energy as heat?
raising the temperature of 100 g of water by 1.0 °C
vaporization of 0.10 g of water at 100 °C
melting 1.0 g of ice at 0 °C
warming 1.0 g of ice from −50 °C to 0 °C (specific heat of ice = 2.06 J/g · K)
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5-81 Compare the number of calories absorbed when 100. g of ice at 0°C is changed to liquid water at 37°C with the number of calories absorbed when 100. g of liquid water is warmed from 0°C to 37°C.
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he enthalpy (H)of vaporization of water is about seven times larger than water’s enthalpy fusion(41kJ/molvs.6kJ/mol). What does this tell us about the relative similarities among the solid, liquid, and gaseous states of water?
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A 1.40-g sample of polyethylene, a common plastic, is dissolved in enough organic solvent to give 100.0 mL of solution. What is the average molar mass of the polymer if the measured osmotic pressure of the solution is 1.86 mm Hg at 25 C?
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