Calculate the molar solubility of CuS in a medium containing H;S at pH=1 and pH=4. KspCus = 6.5x10-30 [H*][HS¯] [H2S] H2S - H* + HS- Ka1 5.7x10-8 [H*][s²-] HS- - H* + S2- Ка2 1.2x10-15 [-SH] [H*]°[s²-] H;S - 2H+ + Sz KaixKa2 - = 6.8x10-23 = [H2S]

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
Problem 13.28QAP
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Calculate the molar solubility of CuS in a medium containing
H2S at pH=1 and pH=4. Kspcus = 6.5x10-30
[H*][HS¯]
[H2S]
H2S - H* + HS-
Ka1
5.7x10-8
Ka2 = 1.2x10-15 =
Каг
[H*][s?-]
[HS-]
HS - H* + S2-
H;S - 2H+ + Sz KaixKa2
[H*]?[s²-]
[H2S]
6.8x10-23
Transcribed Image Text:Calculate the molar solubility of CuS in a medium containing H2S at pH=1 and pH=4. Kspcus = 6.5x10-30 [H*][HS¯] [H2S] H2S - H* + HS- Ka1 5.7x10-8 Ka2 = 1.2x10-15 = Каг [H*][s?-] [HS-] HS - H* + S2- H;S - 2H+ + Sz KaixKa2 [H*]?[s²-] [H2S] 6.8x10-23
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