Cellulose is treated with methanol, which methylates the reducing end of polysaccharides. (a) How many methyl groups would be incorporated per cellulose chain? Explain. (b) Relative to cellulose, how many methyl groups would be incorporated in a molecule of amylopectin? (more, less or the same?) Explain. (c) Cellulose is treated with dimethyl sylfate, which adds a methyl group to all free hydroxyl groups. The cellulose is then hydrolyzed to release all of its monosacharides. Draw the structure of the resulting monosaccharide

Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter15: Carboxylic Acids And Esters
Section: Chapter Questions
Problem 15.57E
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Cellulose is treated with methanol, which methylates the reducing end of
polysaccharides.
(a)
How many methyl groups would be incorporated per cellulose chain?
Explain.
(b)
Relative to cellulose, how many methyl groups would be incorporated in a
molecule of amylopectin? (more, less or the same?) Explain.
(c)
Cellulose is treated with dimethyl sylfate, which adds a methyl group to all
free hydroxyl groups. The cellulose is then hydrolyzed to release all of its
monosacharides. Draw the structure of the resulting monosaccharide
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