Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Alcohols react with sulfonyl chlorides to form sulfonate esters. Only the O-H bond of the alcohol is broken in the reaction, and so no inversion of configuration occurs. The resulting sulfonate esters are reactive in SN1 and SN2 reactions since the sulfonate group is a very weak base and is therefore a good leaving group.

Draw curved arrows to show the movement of electrons in this step of the mechanism.

CH3
CH3
MsCI
OMs
occurs. The resulting sulfonate esters are reactive in Syi and SN2 reactions since the sulfonate group is a very weak base and is therefore a good leaving group
Draw curved arrows to show the movement of electrons in this step of the mechanism.
Arrow-pushing Instructions
Alcohols react with sulfonyl chlorides to form sulfonate esters. Only the O-H bond of the alcohol is broken in the reaction, and so no inversion of configuration
CH3 :0
0:
CH3
:CI:
CH3
он
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Transcribed Image Text:CH3 CH3 MsCI OMs occurs. The resulting sulfonate esters are reactive in Syi and SN2 reactions since the sulfonate group is a very weak base and is therefore a good leaving group Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Alcohols react with sulfonyl chlorides to form sulfonate esters. Only the O-H bond of the alcohol is broken in the reaction, and so no inversion of configuration CH3 :0 0: CH3 :CI: CH3 он
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