# CHAPTER 3. Volumetric Properties of Pure Fluids243.42. For methyl chloride at 100°C the second and third virial coefficients are:B -242.5 cm3.mol -1 C= 25,200 cmo.mol-Calculate the work of mechanically reversible, isothermal compression of 1 mol ofmethyl chloride from 1 bar to 55 bar at 100°C. Base calculations on the followingforms of the virial equation:totВ С+V32(a)ताीdealz=1+tvV2(b)Z 1 B'P + C'P2E0.0-Grst130С -В2Вand C'=В'"wherero boap A BEE11(RT)2RTfaups nisinosWhy don't both equations give exactly the same result?HOS & BRIGEals AC14344

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Step 1

(a)

Write the first virial equation and compare it with the expression for the compressibility factor for methyl chloride at initial conditions considering the process to be Isothermal.

Step 2

Substitute suitable values and obtain the value of initial volume of Methyl Chloride.

Step 3

Similarly, compare the expression for compressibility factor with the first virial equation for final condit...

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