Consider the below reaction mechanism:Step 1: S(s) + O2(g) SO2(g) fast; k1 = rate constant for forward reaction; k-1 = rate constant for reverse reactionFileStep 2: SO2(g) + 1/2 O2(g) SO3(g) slow; k2 = rate constantFileStep 3: SO3(g) + H2O(l) H2SO4(l) fast, k3 = rate constant a) Write the overall reactionb) Identify the intermediaries, if any.c) What is the rate law of the overall reaction?

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 1RQ: Define reaction rate. Distinguish between the initial rate, average rate, and instantaneous rate of...
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Consider the below reaction mechanism:
Step 1: S(s) + O2(g) SO2(g) fast; k1 = rate constant for forward reaction; k-1 = rate constant for reverse reaction
FileStep 2: SO2(g) + 1/2 O2(g) SO3(g) slow; k2 = rate constant
FileStep 3: SO3(g) + H2O(l) H2SO4(l) fast, k3 = rate constant
a) Write the overall reaction
b) Identify the intermediaries, if any.
c) What is the rate law of the overall reaction?

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