Consider the reaction: A → B. Use the below data to determine the first half-life for experiment 1. Please answer in seconds. Initial Rate [M/s] Experiment 4,000 1 2 Incorrect. [A] 0.1 M 0.2 M 0.0025 0.01

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Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 49E: The reaction AB+C is known to be zero order in A and to have a rate constant of 5.0 102 mol/L s at...
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Consider the reaction: A → B.
Use the below data to determine the second half-life for experiment 2. Please answer in seconds.
Experiment
250
1
2
[A]
0.1 M
0.2 M
Initial Rate [M/S]
0.0025
0.01
Incorrect. We learned in the previous problems that this reaction is second order and k = 0.25 M²¹ s²¹.
During the first half-life, [A] decreases by 50% (0.2 M to 0.1M). Now we need to determine how long it will take for [A] decrease by
another 50% (0.1 M to 0.05 M). This means the original concentration for the second half-life of experiment #2 is 0.1 M.
Transcribed Image Text:Consider the reaction: A → B. Use the below data to determine the second half-life for experiment 2. Please answer in seconds. Experiment 250 1 2 [A] 0.1 M 0.2 M Initial Rate [M/S] 0.0025 0.01 Incorrect. We learned in the previous problems that this reaction is second order and k = 0.25 M²¹ s²¹. During the first half-life, [A] decreases by 50% (0.2 M to 0.1M). Now we need to determine how long it will take for [A] decrease by another 50% (0.1 M to 0.05 M). This means the original concentration for the second half-life of experiment #2 is 0.1 M.
Consider the reaction: A → B.
Use the below data to determine the first half-life for experiment 1. Please answer in seconds.
[A]
Experiment
4,000
1
2
Incorrect.
0.1 M
0.2 M
Initial Rate [M/S]
0.0025
0.01
When we double the concentration of A, the rate quadruples. This means that this reaction is second order. Make sure you are using
the correct half-life equation!
*Check to make sure you are using the data from Experiment #1.
Transcribed Image Text:Consider the reaction: A → B. Use the below data to determine the first half-life for experiment 1. Please answer in seconds. [A] Experiment 4,000 1 2 Incorrect. 0.1 M 0.2 M Initial Rate [M/S] 0.0025 0.01 When we double the concentration of A, the rate quadruples. This means that this reaction is second order. Make sure you are using the correct half-life equation! *Check to make sure you are using the data from Experiment #1.
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