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- A sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCl and NaCl weighing 0.1801 g. These chlorides are dissolved in H2O, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.1000N KCNS, with ferric alum as indicator. Calculate the percentage of K2O in the silicate.In the synthesis of hydrocarbons, the carbon source is carbon dioxide. Although the CO2 concentra?on in the atmosphere raises at a drama?c speed, point sources are probably the easier sources for a PtX process. Iden?fy 3 possible point sources, explain why CO2 is formed and what challenges each of the three CO2 streams presentsA 50 mL sample solution containing 8-hydroxyquinoline (MW: 145) was analyzed by adding 25 ml, 0.1 M KBrO3, excess KBr and acidified. The mixture was left for 10 minutes in dark place. After this time KI in excess was added followed by titration with 27.9 mL, 0.05 M thiosulfate standard solution. Write balance equations? What is the percent w/v 8-hydroxyquinoline in sample?
- Calculate the solubility of lead(II) sulfate (Ksp = 2.53x10-8) in a 0.0034 M solution of sodium sulfate. Give your answer to three sig. figs. and in exponential form (e. g. 1.23E-3).A pH probe/meter uses the following equations: Ecell = L + 0.0592 log a1 = L - 0.0592 pH Where L = L1 + EAg/AgCI + Easy= constants L1 = - 0.0592 log a2 a1 = activity of analyte solution a2 = activity of internal solution Questions: How will measured pH value be affected vs “real” pH if the temperature of the sample is 30C when pH was measured? How will measured pH value be affected vs “real” pH if HCl in pH electrode, became 0.15M instead of 0.1M? How pH value will be affected vs “real” pH if the glass of the pH electrode is not fully hydrated? Please answer all questions and provide a brief explanationFor Indirect Iodometric Analysis of Copper... ~0.0896g KIO3 necessary to consume 350mL of 0.1 M Na2S2O3, Na2S2O3 is stored in an amber glass bottle until ready for use. Primary Standard KIO3 has 2g of KI, 50mL of DI water, and 10 mL of 1.0M HCl is added then immediately titrated with Na2S2O3 until medium yellow or straw... then 5mL of starch indicator is added and titrated again until blue black color turns clear. Unknown CuO use 1.2G of Unknown, 20mL of HNO3 heated until sample dissolved, 25 mL of DI water added and boiled until clear light blue color, after cooling 1:1 NH3 added (~34.47 mL of NH4OH reagent) until permanent deep blue color amine complex, 2g of NH4HF2 added and swirled until dissolved, 3 g of KI is added then titrated immediately with Na2S2O3 until brown color of iodide is nearly gone (brown milk color), 2 g of KSCN and 3 mL of starch indicator is then added with titration continuing until disappearance of new blue black color. 1. Na2CO3 is often added to thiosulfate…
- For Indirect Iodometric Analysis of Copper... ~0.0896g KIO3 necessary to consume 350mL of 0.1 M Na2S2O3, Na2S2O3 is stored in an amber glass bottle until ready for use. Primary Standard KIO3 has 2g of KI, 50mL of DI water, and 10 mL of 1.0M HCl is added then immediately titrated with Na2S2O3 until medium yellow or straw... then 5mL of starch indicator is added and titrated again until blue black color turns clear. Unknown CuO use 1.2G of Unknown, 20mL of HNO3 heated until sample dissolved, 25 mL of DI water added and boiled until clear light blue color, after cooling 1:1 NH3 added (~34.47 mL of NH4OH reagent) until permanent deep blue color amine complex, 2g of NH4HF2 added and swirled until dissolved, 3 g of KI is added then titrated immediately with Na2S2O3 until brown color of iodide is nearly gone (brown milk color), 2 g of KSCN and 3 mL of starch indicator is then added with titration continuing until disappearance of new blue black color. 4. Why is the starch indicator solution…Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.Please answer atleast 4 sub-parts. Thank you.
- The amount of iron in a meteorite was determined by a redox titration using KMnO4 as the titrant. A 0.4185 -g sample was dissolved in acid and the liberated Fe3+ quantitatively reduced to Fe2+, using a reductor column. Titrating with 0.0051 M KMnO4 requires 23.44 mL to reach the end point. Determine the %w/w Fe2O3 in the sample of meteorite. (Fe = 55.845 amu, Fe2O3 = 159.69 g/molAn acid solution containing 2 per cent by mass of NaNO3, and an unknown concentration of HNO3 is used to regenerate a strong acid resin. After sufficient acid had been passed over the resin for equilibrium to attained, analysis showed that 10 per cent of resin sites were occupied by sodium ions. What was the concentration of HNO3 in the solution, if its density were 1,030 kg/cu.m.?A sample of steel (0.506 g) was digested in acid and the solution made up to 100 cm3 with deionised water. Aliquots (25.0 cm3) of this solution were transferred into two volumetric flasks (100 cm3) labelled A and B. Flask A was made up to volume with deionised water. To flask B was added 10.0 cm3 of a 260 ppm standard solution of Mn2+ which was then also made up to volume with deionised water. The following absorbance results were obtained: Solution A = 0.356, Solution B = 0.578. Use these results to calculate the percentage (% w/w) of manganese in the steel sample.
