Dihydroxylation of an alkene can be carried out with H2O2 in HCO2H. In this reaction, trans-but-2-ene affords (2R,3S)- butane-2,3-diol, whereas cis-but-2-ene affords a mixture of (2R,3R)-butane-2,3-diol and (2S,3S)-butane-2,3-diol. Does dihydroxylation by this method occur with syn or anti addition?
Dihydroxylation of an alkene can be carried out with H2O2 in HCO2H. In this reaction, trans-but-2-ene affords (2R,3S)- butane-2,3-diol, whereas cis-but-2-ene affords a mixture of (2R,3R)-butane-2,3-diol and (2S,3S)-butane-2,3-diol. Does dihydroxylation by this method occur with syn or anti addition?
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.42P: Bicyclo-2,5-heptadiene can be prepared in two steps from cyclopentadiene and vinyl chloride. Provide...
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Dihydroxylation of an
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