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do 22 with explanation

do 22 with explanation

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.37P
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( do 22 with explanation
4.20. SOLI No par 1. alkane becaus (no M') 30 4 50 60 70 80 90 100 110 120 130 140 m/z Fig. 4.14 17. (a) Explain how to detect the presence of (i) Br (ii) Cl and (III) I in a molecule CH mass spectrometry | 43 | CH;CH,CH,Br 80 (b) Give the relative 60 spectrum of 40 41 20- Deduce 15 the of 10 20 80 90 100 110 the 30 40 50 60 70 miz Fig. 4.15 O Scanned with Oken Scanner Relative abundance レマ డి O Scanned with Oken Scanner 4/4 Mass Spectroscopy 195 compound (A). 100 43 CH;CHCH; Č! 50 Tat bro eb a 41 63 78 65 80 de ager e'ello 0 bdsbis n 10 20 30 40 50 60 70 80 90 100 ofoM Relative abundance miz Fig. 4.16 20. Compound (A) C;H120 is an alcohol. It shows prominent peaks at mle = 88 (M*), 55, 42 (base peak), 31 and 29. Give the structure of the compound. 21. Compound (A) C¸H1,O is an alcohol. It does not show molecular ion peak. The peaks shown by this compound are at mle = 59 (base peak) 41, 29 and 27. What will be the structure of compound (A) ? 22. Methyl salicylate exhibits peaks at mle = 152 (M*), 121, 120, 92, 65 and 64. Explain the formation of ions corresponding to these peaks. 4.20. SOLUTIONS. Relat 1.Jahoin
Transcribed Image Text:4.20. SOLI No par 1. alkane becaus (no M') 30 4 50 60 70 80 90 100 110 120 130 140 m/z Fig. 4.14 17. (a) Explain how to detect the presence of (i) Br (ii) Cl and (III) I in a molecule CH mass spectrometry | 43 | CH;CH,CH,Br 80 (b) Give the relative 60 spectrum of 40 41 20- Deduce 15 the of 10 20 80 90 100 110 the 30 40 50 60 70 miz Fig. 4.15 O Scanned with Oken Scanner Relative abundance レマ డి O Scanned with Oken Scanner 4/4 Mass Spectroscopy 195 compound (A). 100 43 CH;CHCH; Č! 50 Tat bro eb a 41 63 78 65 80 de ager e'ello 0 bdsbis n 10 20 30 40 50 60 70 80 90 100 ofoM Relative abundance miz Fig. 4.16 20. Compound (A) C;H120 is an alcohol. It shows prominent peaks at mle = 88 (M*), 55, 42 (base peak), 31 and 29. Give the structure of the compound. 21. Compound (A) C¸H1,O is an alcohol. It does not show molecular ion peak. The peaks shown by this compound are at mle = 59 (base peak) 41, 29 and 27. What will be the structure of compound (A) ? 22. Methyl salicylate exhibits peaks at mle = 152 (M*), 121, 120, 92, 65 and 64. Explain the formation of ions corresponding to these peaks. 4.20. SOLUTIONS. Relat 1.Jahoin
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