Draw the major monobromination product when the following alkane is subjected to radical bromination at 25 °C. If there is more than one product, both may be drawn in the same box. Br light
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- What is the major product in the reaction below? Draw the complete curved-arrow mechanism to show the formation of the major product.Draw all the monochlorination products, including stereoisomers, that are formed from radical chlorination of the following compound:Draw the major monobromination product when the alkane shown is subjected to radical bromination at 25 °C. My answer is in the red box, but it is incorrect. Thank you.
- In the presence of a radical initiator (Z•), tributyltin hydride (R3SnH, R = CH3CH2CH2CH2) reduces alkyl halides to alkanes: R′X + R3SnH → R′H + R3SnX. The mechanism consists of a radical chain process with an intermediate tin radical: This reaction has been employed in many radical cyclization reactions. Draw a stepwise mechanism for the following reaction.Draw the major product(s) from addition of HBr to the alkene below.Write the mechanism of the following bromination reaction and explain the regioselectivity of the bromination reaction. Draw the mechanism, transition state, energy diagram, etc. The same reaction with chlorine is not much regioselective in Q1. Explain the decreased regioselectivity of the following chlorination reaction by comparing the bromination reaction in Q1. Draw the mechanism, transition state, energy diagram, etc.
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- A student adds NBS to a solution of 1-methylcyclohexene and irradiates the mixture with a sunlamp until all the NBS has reacted. After a careful distillation, the product mixture contains two major products of formula C7H11Br. Draw the products obtained from each free-radical intermediate.Complete the following reactions by providing the missing product(s). Determine what mechanism operates in each case (SN1, SN2, E1, or E2). Show the stereochemistry of the product(s) where appropriate. If more than one product is formed circle the major one.In the box to the left of each reaction below, write the mechanism by which it occurs (could be SN1, SN2, or E1, or even 2 of them). Then draw the product(s).