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Organic Chemistry: A Guided Inquiry

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 4E

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Draw the structure(s) of the major organic product(s) of the following reaction.
1. Dry Et,0 at -60°
2. aqueous NH,Cl at 0°
• Use the wedge/hash bond tools to indicate stereochemistry where it exists.
• If the reaction produces a racemic mixture, draw both stereoisomers.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
• Include anionic counter-ions, e.g., I, in your answer, but draw them in their own sketcher.

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Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. Use the wedge/hash bond tools to indicate stereochemistry where it exists. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after aqueous workup. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
Need help with this SN2 esterification reaction mechanism with pushing arrows. Please help.
Draw the structure of the major organic product(s) of the reaction. You do not have to consider stereochemistry. All carboxyl and amino groups should be drawn in the neutral form. If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
Draw the structure of the major organic product(s) of the reaction. You do not have to consider stereochemistry. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
Rearrangements can occur during the dehydration of 1° alcohols even though no 1° carbocation is formed—that is, a 1,2-shift occurs as the C— OH2+ bond is broken, forming a more stable 2° or 3° carbocation, as shown in Equation [1]. Using this information, draw a stepwise mechanism for the reaction shown in Equation [2]. We will see another example of this type of rearrangement in Section 16.5C.
Draw the organic product(s) of the following reaction. You do not have to consider stereochemistry. Include cationic counter-ions, e.g., Na+ in your answer, but draw them in their own sketcher. If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-down menu.
please help with part B:
i. Fill in the missing starting materials, products, or reagents as necessary. ii. Label each transformation as SN1, SN2, or acid/base. iii. Indicate if the product is racemic or a single enantiomer
First image directions are "Fill in the blanks with the major organic product(s). Make sure to indicate stereochemistry in your drawings where appropriate." Second image directions are "Fill in the blanks with the major organic product or starting material(s)."
IUPAC NAMING and Indicate the stereochemistry if E or Z. Write the complete solution
Assume that 2-chloropropane reacts with CN− in an SN2 reaction. Use the JSME editor () to draw the structure of the substitution product of the reaction. The guide on how to draw your structure can be found here Important Note: When drawing the structures in the JME editor please adhere to the following formats: 1. If the nucleophile is OH−, DO NOT manually add the "H" to the final product 2. If the nucleophile is CN−, be sure to include the appropriate bonding between the C and N in the final product

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