#3 Organic ChemistryMaxwellpresented by Macmillan LearningDraw the structures of the starting materials needed to make 2-methylhept-3-yne or 2-methyl-3-heptyne. The startingmaterials may be any bromoalkane having five carbons or fewer.2 equiv. NaNH2in mineral oilNaNH,reagent CStartingMaterial AheatLiquid NH3Na*finalintermediate Bintermediate CproductDraw Starting Material A. The starting hydrocarbon mustDraw reagent C, which must be a bromoalkane with fivebe a bromoalkane with five carbons or fewer.carbons or fewer.Select Draw Rings MoreEraseSelect Draw Rings MoreErase|7 Cс | н | BrHBr

If the two halogens on the same carbon atom then its called as geminal dihalide Hence the…

Draw the structures of the starting materials needed to make 2-methylhept-3-yne or 2-methyl-3-heptyne. The starting materials may be any bromoalkane having five carbons or fewer. 2 equiv. NaNH2 in mineral oil NaNH2 reagent C Starting Material A heat Liquid NH3 Na* H final intermediate B intermediate C product Draw Starting Material A. The starting hydrocarbon must Draw reagent C, which must be a bromoalkane with five be a bromoalkane with five carbons or fewer. carbons or fewer.

Draw the structures of the starting materials needed to make 2-methylhept-3-yne or 2-methyl-3-heptyne. The starting materials may be any bromoalkane having five carbons or fewer. 2 equiv. NaNH2 in mineral oil NaNH2 reagent C Starting Material A heat Liquid NH3 Na* H final intermediate B intermediate C product Draw Starting Material A. The starting hydrocarbon must Draw reagent C, which must be a bromoalkane with five be a bromoalkane with five carbons or fewer. carbons or fewer.

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter22: Organic And Biological Molecules

Section: Chapter Questions

Problem 46E: There are three isomers of dichlorobenzene, one of which has now replaced naphthalene as the main...

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1. Using Br2 in C2H4Br2 will result in HBr and ______. a. C2H3Cl3 b. C2H4Cl3 c. C2H2Cl3 d. none of the above 2. How many halogenation are posible in propane? a. 3 b. 8 c. 6 d. 10 3.Sulfonation of pentane will result in ________ and water. a. C5H11SO3H b. C5H12SO3H c. C5H14SO3H d. none of the above 4.Nitration of hexane will result in ________ and water. a. C6H13SO3H b. C6H15NO2 c. C6H13NO2 d. C6H14NO2 5.How many moles of O2 in heating a C12H26 (dodecane) a. 27 b. 37 c. 24 d. none of the above
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A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions
a. Draw and name all of the isomeric products obtainedfrom the monobromination of propane with Br2/light. If halogenation were a completely randomreaction and had an equal probability of occurring atany of the C—H bonds in a molecule, what percentage of each of these monobromo products would beexpected?b. Answer part (a) using 2-methylpropane as the starting material.
OChem HELP... Draw the conformational structures (chair or boat conformations) for the MAJOR product formed when 1-tert-butylcyclohexene reacts with each of the following reagents. Also, indicate if the product obtained is racemic form. a) Br2, CCl4 b) Br2, H2O c) OsO4, then aqueous NaHSO3 d) ICl e) mCPBA, then H3O+, H20 f) O3, then Me2S (conformational structure not required) g) BH3:THF, then H2O2, HO- h) D2, Pt i) Hg(OAc)2 in THF-H2O, then NaBH4, HO- j) BD3 :THF, then CH3CO2T
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Table 6.4. Oxidation: Reaction with Baeyer’s reagent (cold, dilute, neutral, aqueous KMnO4) Write (+) if the reaction is positive, (-) if negative. SAMPLE OBSERVATIONS +/- cyclohexane cyclohexene benzene toluene acetylene Enumerate the classes of hydrocarbons that are oxidizable by Baeyer’s reagent. ________________________________________________________________________ ________________________________________________________________________ What is the structural feature of these classes of hydrocarbons? ________________________________________________________________________ ________________________________________________________________________
A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2 CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under the same conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C. Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structures of A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions.
Which of the following is most soluble in basic medium? a. cyclopropane b. 1,3-cyclobutadiene c. 1,3-cyclopentadiene d. benzene
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1,4-Pentadiene (CH2=CH-CH2-CH=CH2) is a liquid at room temperature and has a density of 0.66 g/mL and molar mass of 68.12 g/mol. In a laboratory experiment, 3.80 mL of this compound was treated with 4.80 mL of conc. H2SO4 (100% w/w; molar mass 98.08 g/mol). Note that the density of conc. H2SO4 is 1.84 g/mL. The resulting sulfate ester was then treated with 1.20 mL of water (molar mass 18.02 g/mol) affording, after work- up, 2,4-pentanediol (molar mass 104.15 g/mol) as the crude product. The crude product was then purified by simple distillation, which yielded 2.00 g of pure product. What is the theoretical yield of 2,4-pentanediol expressed in grams? Show calculations. What is the percentage yield of pure 2,4-pentanediol?
1,4-Pentadiene (CH2=CH-CH2-CH=CH2) is a liquid at room temperature and has a density of 0.66 g/mL and molar mass of 68.12 g/mol. In a laboratory experiment, 3.80 mL of this compound was treated with 4.80 mL of conc. H2SO4 (100% w/w; molar mass 98.08 g/mol). Note that the density of conc. H2SO4 is 1.84 g/mL. The resulting sulfate ester was then treated with 1.20 mL of water (molar mass 18.02 g/mol) affording, after work- up, 2,4-pentanediol (molar mass 104.15 g/mol) as the crude product. The crude product was then purified by simple distillation, which yielded 2.00 g of pure product. a. Provide a balanced chemical equation to show the reaction between 1,4-pentadiene and sulfuric acid. Do not use molecular formulas in the chemical equation except for sulfuric acid. b. What reactant is the limiting reagent in this chemical equation? Show calculations to support your answer.