Estimate the specific volume of water at temperatures ?1 = 300℃ for the following pressures: p1 = 400 kpa using : (a) Van de Waals constitutive eq. (b) Redlich Kwong constitutive eq. (c) Lee and Kesler correlation for compressibility factor (d)Ideal gas eq. (e) Thermodynamic tables. Before starting the computations, evaluate the state of water for each case, in order to justify the use of the constitutive equations for real/ideal gases. In other words, we need to know if water is a gas under these conditions, in order to do meaningful computations. Make a comment about which results are more reliable and which approximation is more accurate.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Estimate the specific volume of water at temperatures ?1 = 300℃ for the following pressures: p1 = 400 kpa using : (a) Van de Waals constitutive eq. (b) Redlich Kwong constitutive eq. (c) Lee and Kesler correlation for compressibility factor (d)Ideal gas eq. (e) Thermodynamic tables. Before starting the computations, evaluate the state of water for each case, in order to justify the use of the constitutive equations for real/ideal gases. In other words, we need to know if water is a gas under these conditions, in order to do meaningful computations. Make a comment about which results are more reliable and which approximation is more accurate.

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Given that

Temperature T = 300 C

Pressure P = 400 kPa

We need to find the specific volume of this water gas when the gas behaves as (a) Vanderwall (b) Redlich Kwong (c) Lee Kesler

 

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