For both redox reactions balance them using the half reaction method Cu(NH3)42++ S2O42----> SO32-+Cu+NH3 (basic solution) MnO4-+S2O32----> S4O62- + Mn2+ (acid solution)

Fundamentals Of Analytical Chemistry
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Author:Skoog
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Chapter18: Introduction To Electrochemistry
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For both redox reactions balance them using the half reaction method

Cu(NH3)42++ S2O42----> SO32-+Cu+NH3 (basic solution)

MnO4-+S2O32----> S4O62- + Mn2+ (acid solution)

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