Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few moles of carbon dioxide (CO₂) gas. A few moles of carbon dioxide (CO₂) gas. A few grams of liquid water (H₂O). Change The carbon dioxide expands from a volume of 1.0 L to a volume of 3.0 L while the temperature is held constant at 82.0 °C. The carbon dioxide is cooled from 77.0 °C to 8.0 °C and is also expanded from a volume of 2.0 L to a volume of 12.0 L. The water is heated from -12.0 °C to 63.0 °C. оо O ооо OO AS AS 0 not enough information AS 0 not enough information AS 0 not enough informationarrow_forwardQ7. For each reaction, predict the sign of entropy of system and find the value of ASuniv. a. 3NO (g) N₂O (g) + NO2 (g) b. P4 (g) +5 Oz (g) → P4010 (S) c. Combustion of ethane (C2H6) gas to form carbon dioxide and gaseous water.arrow_forwardFor eac em listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few moles of carbon dioxide (CO₂) gas. A few grams of liquid ammonia (NH3). A few moles of helium (He) gas. Change The carbon dioxide is cooled from 73.0 °C to 8.0 °C while the volume is held constant at 8.0 L. The ammonia evaporates at a constant temperature of 53.0 °C. The helium is cooled from 66.0 °C to 8.0 °C and is also compressed from a volume of 13.0 L to a volume of 10.0 L. ΔS AS 0 not enough information AS 0 not enough information AS 0 not enough information ( [U::: OL Earrow_forward
- 1. Ammonia can be made from the reaction of nitrogen and hydrogen: N2 (g) + 3 H2 (g) ⟺ 2 NH3 (g) For this reaction, K = 1.6 x 102 and ΔH = -91.8 kcal/mole at 25oC. Is the reaction endothermic or exothermic? Briefly explain. Is there in increase in entropy, a decrease in entropy, or no change in entropy? Briefly explain. At 25oC, is this reaction product favored or reactant favored? Briefly explain. Do you expect this reaction to be spontaneous at all temperatures? Briefly explain.arrow_forwardFor each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S , or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System Change S A few moles of carbon dioxide (CO2) gas. The carbon dioxide is heated from 9.0 °C to 36.0 °C and also expands from a volume of 6.0 L to a volume of 14.0 L. <S0 =S0 >S0 not enough information A few moles of helium (He) gas. The helium expands from a volume of 9.0 L to a volume of 15.0 L while the temperature is held constant at 20.0 °C. <S0 =S0 >S0 not enough information A few grams of liquid ammonia (NH3). The ammonia is heated from -1.0 °C to 2.0 °C. <S0…arrow_forwardFor each of the following changes, do you expect the entropy to increase or decrease? (These questions do not require calculations.) a. Ammonia gas and hydrogen chloride gas react to deposit solid ammonium chloride on a surface b. Two aqueous solutions are combined to form a precipitate c. Methanol gas condenses to form liquid methanol d. Butane liquid reacts with oxygen gas to form carbon dioxide gas and gaseous water e. Liquid water freezes to form ice f. Solid lead melts g. A solid solute dissolves in a liquid solvent h. Liquid water boils Possible answers: 1. Entropy should increase (more positive) 2. Entropy should decrease (more negative) 3. The change in entropy cannot be determined from the information givenarrow_forward
- 1:44 1 LTE 4 1 Search Question 20.b of 23 Show Answer Consider the reaction Cl2(g) + Br2(g) → 2 BrCI(g) at 25 °C. Which of the following best explains why the change in entropy is so small? A) All of the components in the chemical equation are gases. B) There are the same moles of gas on both sides of the reaction. C) The temperature of the reaction does not change. Tap here or pull up for additional resourcesarrow_forwardFor each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few grams of ammonia vapor (NH3). A few moles of nitrogen (N₂) gas. A few moles of nitrogen (N₂) gas. Change The ammonia condenses to a liquid at a constant temperature of -8.0 °C. The nitrogen is cooled from 78.0 °C to 3.0 °C while the volume is held constant at 2.0 L. The nitrogen is heated from -16.0 °C to 12.0 °C and also expands from a volume of 1.0 L to a volume of 10.0 L. AS AS 0 not enough information AS 0 O not enough information O AS 0 not enough information Śarrow_forwardFor each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few moles of carbon dioxide (CO₂) gas. A few grams of liquid ammonia (NH3). A few moles of carbon dioxide (CO₂) gas. Change The carbon dioxide expands from a volume of 10.0 L to a volume of 13.0 L while the temperature is held constant at 57.0 °C. The ammonia evaporates at a constant temperature of 11.0 °C. The carbon dioxide is cooled from 87.0 °C to -2.0 °C and is also expanded from a volume of 8.0 L to a volume of 11.0 L. AS AS 0 not enough information AS 0 not enough information AS 0 not enough informationarrow_forward
- Which one of the following choices of gaseous molecules is rank ordered correctly from lowest standard molar entropy (left hand side) to highest standard molar entropy (right hand side)? He, Ne, CO, SiH4 SiH4 , CO, Ne, He SiH4 , Ne, CO, He CO, SiH4 , Ne, Hearrow_forwardFor each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few moles of helium (He) gas. A few moles of carbon dioxide (CO₂) gas. A few moles of carbon dioxide (CO₂) gas. Change The helium is compressed from a volume of 11.0 L to a volume of 4.0 L while the temperature is held constant at -6.0 °C. The carbon dioxide is heated from -17.0 °C to 53.0 °C while the volume is held constant at 8.0 L. The carbon dioxide is heated from -8.0 °C to 3.0 °C and also expands from a volume of 10.0 L to a volume of 12.0 L. x AS AS 0 not enough information O AS 0 not enough information O AS 0 not enough informationarrow_forwardFor each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave Sunchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. System A few moles of carbon dioxide (CO₂) gas. A few grams of liquid acetone ((CH₂)₂CO). A few moles of helium (He) gas. Change The carbon dioxide is heated from 5.0 °C to 64.0 °C and is also compressed from a volume of 14.0 L to a volume of 8.0 L. The acetone is heated from -12.0 °C to 89.0 °C. The helium is heated from -14.0 °C to 44.0 °C while the volume is held constant at 9.0 L. X O AS 0 not enough O information O AS 0 not enough information AS 0 O O O O AS O not enough O informationarrow_forward
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