HF(aq)+ H2O(l)→ F−(aq)+ H3O+(aq)   At a certain temperature, a chemist finds that a 3.6L reaction vessel containing an aqueous solution of hydrofluoric acid, water, fluoride anion, and hydronium cation at equilibrium has the following composition:   compound amount HF 1.68g H2O 575.g F− 0.437g H3O+ 0.257g Calculate the value of the equilibrium constant Kc for this reaction

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.25PAE
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QUESTION#1:

Stoichiometry

TOPIC NAME:

Calculating an equilibrium constant from a heterogeneous equilibrium composition

Hydrofluoric acid and water react to form fluoride anion and hydronium cation, like this:

HF(aq)+ H2O(l)F−(aq)+ H3O+(aq)
 
At a certain temperature, a chemist finds that a 3.6L reaction vessel containing an aqueous solution of hydrofluoric acid, water, fluoride anion, and hydronium cation at equilibrium has the following composition:
 
compound amount
HF
1.68g
H2O
575.g
F−
0.437g
H3O+
0.257g

Calculate the value of the equilibrium constant Kc for this reaction. Round your answer to 2 significant digits.

Kc=
 
 
 

 

QUESTION#2:

Advanced Material

TOPIC NAME:

Using reactant reaction order to predict changes in initial rate

A certain reaction is first order in N2 and second-order in H2. Use this information to complete the table below. Round each of your answers to 3 significant digits.

N2
H2
initial rate of reaction
2.08M
1.74M
×7.00104/Ms
0.500M
1.74M
 ? M/s
5.06M
0.715M
 ? M/s
 
 
 

 

QUESTION#3

Advanced Material

TOPIC NAME:

Using a rate law

 

The rate of a certain reaction is given by the following rate law:

 

rate

=kH22NH3

Use this information to answer the questions below.

What is the reaction order in H2?
?
What is the reaction order in NH3?
?
What is overall reaction order?
?
At a certain concentration of H2 and NH3, the initial rate of reaction is 0.490 M / s. What would the initial rate of the reaction be if the concentration of H2 were doubled? Round your answer to 
3 significant digits .
 ? M/s
The rate of the reaction is measured to be 17.0 M / s when [H2] = 1.3 M and [NH3] = 0.71 M. Calculate the value of the rate constant. Round your answer to 
2 significant digits.
k= ? ⋅M−2s−1
 
 
 
 

*****PLEASE ANSWER ALL QUESTIONS CORRECTLY and if possible please round to its significant digits. I really need this.*****

 

**ALSO PLEASE BE CLEAR SO I CAN UNDERSTAND!**

 
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ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning