How large a change in energy (or enthalpy) of reaction is needed for an acid ionization to lower the pKa by one unit at 25°C? Assume that the entropy of ionization is unchanged. (We use unprimed variables to indicate the reaction with the lower pKa, or higher Ka.)

Chemistry & Chemical Reactivity
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ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section: Chapter Questions
Problem 110IL
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How large a change in energy (or enthalpy) of reaction is needed for an acid ionization to lower the pKa by one unit at 25°C? Assume that the entropy of ionization is unchanged. (We use unprimed variables to indicate the reaction with the lower pKa, or higher Ka.)

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