In the presence of O2, NO reacts with sulfur-containing proteins to form S-nitrosothiols, such as C6H13SNO. This compound decomposes to form a disulfide and NO:2C6HSNO(aq)------>2NO(g)+C12H26S2(aq) The following data were collected for the decomposition reaction at 100°C. Time (s) [C6H13SNO] (aq) 0 1.08 x 10-3 10 7.77 x 10-4 20 5.46 x 10-4 30 3.79 x 10-4 Calculate the value of the first-order rate constant for the reaction.
In the presence of O2, NO reacts with sulfur-containing proteins to form S-nitrosothiols, such as C6H13SNO. This compound decomposes to form a disulfide and NO:2C6HSNO(aq)------>2NO(g)+C12H26S2(aq) The following data were collected for the decomposition reaction at 100°C. Time (s) [C6H13SNO] (aq) 0 1.08 x 10-3 10 7.77 x 10-4 20 5.46 x 10-4 30 3.79 x 10-4 Calculate the value of the first-order rate constant for the reaction.
Chemistry by OpenStax (2015-05-04)
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Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter12: Kinetics
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In the presence of O2, NO reacts with sulfur-containing proteins to form S-nitrosothiols, such as C6H13SNO. This compound decomposes to form a disulfide and NO:
2C6HSNO(aq)------>2NO(g)+C12H26S2(aq)
The following data were collected for the decomposition reaction at 100°C.
Calculate the value of the first-order rate constant for the reaction.
| Time (s) | [C6H13SNO] (aq) |
|---|---|
| 0 | 1.08 x 10-3 |
| 10 | 7.77 x 10-4 |
| 20 | 5.46 x 10-4 |
| 30 | 3.79 x 10-4 |
Calculate the value of the first-order rate constant for the reaction.
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