It turns out that the van der Waals constant b equals fourtimes the total volume actually occupied by the moleculesof a mole of gas. Using this figure, calculate the fraction of the volume in a container actually occupied by Ar atoms(a) at STP, (b) at 200 atm pressure and 0 °C. (Assume forsimplicity that the ideal-gas equation still holds.)

Chemistry & Chemical Reactivity
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Chapter10: Gases And Their Properties
Section: Chapter Questions
Problem 53PS: In the text, it is stated that the pressure of 4.00 mol of Cl2 in a 4.00-L tank at 100.0 C should be...
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It turns out that the van der Waals constant b equals four
times the total volume actually occupied by the molecules
of a mole of gas. Using this figure, calculate the fraction of the volume in a container actually occupied by Ar atoms
(a) at STP, (b) at 200 atm pressure and 0 °C. (Assume for
simplicity that the ideal-gas equation still holds.)

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