( do a b c d ) On the basis of the 18-electron rule, identify the first-rowtransition metal for each of the following:a. [M(CO);]+b. H;CM(CO)sc. M(CO),(CS)(PPh;)Brd. [(7-C,H)(7°-C;H3)M(CO)]OCH3(OC),M=C`C¢H5е.f. [(n-C,H4)(n°-CsH3)M]*g. (7°-C,H3(n°-C;H3)M(CH;)(NO) (has linearly coor-dinated NO)h. [M(CO),I(diphos)]¯(diphos = 1,2-bis(diphenylphosphino)ethane)

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Answered: On the basis of the 18-electron rule,…

On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: a. [M(CO);]+ b. H;CM(CO), c. M(CO),(CS)(PPh;)Br d. [(7-C,H;)(n°-CgH;)M(CO)]

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry

Section: Chapter Questions

Problem 22.20QAP

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Question

( do a b c d )

On the basis of the 18-electron rule, identify the first-row
transition metal for each of the following:
a. [M(CO);]+
b. H;CM(CO)s
c. M(CO),(CS)(PPh;)Br
d. [(7-C,H)(7°-C;H3)M(CO)]
OCH3
(OC),M=C
`C¢H5
е.
f. [(n-C,H4)(n°-CsH3)M]*
g. (7°-C,H3(n°-C;H3)M(CH;)(NO) (has linearly coor-
dinated NO)
h. [M(CO),I(diphos)]¯
(diphos = 1,2-bis(diphenylphosphino)ethane)

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