Peroxyacyl nitrates contain two relatively weak bonds that can be broken by low-energy photons. The weakest is the N−O bond in the nitrate functional group of the molecule with a standard bond-dissociation energy of 201 kJ/mol. What is the longest wavelength of a photon, in nanometers, that has enough energy to cause the photodissociation of the weakest bond. Assume all energy of the photon is efficiently used for the photodissociation.
Peroxyacyl nitrates contain two relatively weak bonds that can be broken by low-energy photons. The weakest is the N−O bond in the nitrate functional group of the molecule with a standard bond-dissociation energy of 201 kJ/mol. What is the longest wavelength of a photon, in nanometers, that has enough energy to cause the photodissociation of the weakest bond. Assume all energy of the photon is efficiently used for the photodissociation.
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.73PAE
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Peroxyacyl nitrates contain two relatively weak bonds that can be broken by low-energy photons. The weakest is the N−O bond in the nitrate functional group of the molecule with a standard bond-dissociation energy of 201 kJ/mol. What is the longest wavelength of a photon, in nanometers, that has enough energy to cause the photodissociation of the weakest bond. Assume all energy of the photon is efficiently used for the photodissociation.
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