Question
Asked Jun 11, 2019
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Please
the follawa Componds
Synthesize
tram benzene
Notc A Friedel -Crafts alky la tro wont wer
rearranste es
hert becuse o
ISo buhy a up in tw ment. Make the
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Please the follawa Componds Synthesize tram benzene Notc A Friedel -Crafts alky la tro wont wer rearranste es hert becuse o ISo buhy a up in tw ment. Make the

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Expert Answer

Step 1

The synthesis of 4-chloro toluene involves two reaction, first Friedel-Crafts alkylation and then halogenation reaction. As the -CH3(methyl) is ortho and para directing so incoming group is directed to these positions.

The reaction is shown as follows:

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CH3 cH3 ch3 CHsCA + A&Chs ARCks Cl

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Step 2

The synthesis of 3-methyl acetophenone is taken place in two steps, first is the Friedel-Crafts alkylation and then followed by Friedel-Crafts acylation reaction.

The reaction is shown as follows:

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CH3 CH3 CH2-C-CE CH2 CA AIca FaChs AJCI3 C-CH Il

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Step 3

The synthesis of 1-chloro-3-isobutylbenzene is taken place in four steps, first the addition of alkyl group with the help of Friedel-Crafts alkylation.

Since the alkyl group is ortho, para directing group hence the Sulfonation of benzene is taken place with the help of SO3(excess) in the pres...

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CH3 CA-CHICH-C3 SO3 (exen) H2SO4 rechlcas So H H2SO4 903H soH

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