Propylene forms only oligomer under normal free radical conditions, yet the monomer forms high-molecular-weight polymer if it is polymerized while trapped in the channels of a crystalline host substance such as urea or thiourea. Explain

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter31: Synthetic Polymers
Section31.1: Chain-growth Polymers
Problem 1P: Order the following monomers with respect to their expected reactivity toward cationic...
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Propylene forms only oligomer under normal free radical conditions, yet the monomer forms high-molecular-weight polymer if it is polymerized while trapped in the channels of a crystalline host substance such as urea or thiourea. Explain [G. Di Silvestro, P. Sozzani, and M. Farina, Polym. Preprints, 27(1), 92, 1986].

Propylene forms only oligomer under normal free radical conditions, yet the monomer forms
high-molecular-weight polymer if it is polymerized while trapped in the channels of a crystalline
host substance such as urea or thiourea. Explain [G. Di Silvestro, P. Sozzani, and M. Farina,
Polym. Preprints, 27(1), 92, 1986].
Transcribed Image Text:Propylene forms only oligomer under normal free radical conditions, yet the monomer forms high-molecular-weight polymer if it is polymerized while trapped in the channels of a crystalline host substance such as urea or thiourea. Explain [G. Di Silvestro, P. Sozzani, and M. Farina, Polym. Preprints, 27(1), 92, 1986].
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