Provide explanations for the number of intense perchlorate Cl-O stretching vibrational modes observed in the IR of the following three silver(I) complexes.  explain briefly  1) The perchlorate anion in Ag(NH3)2(ClO4) has a single intense Cl-O stretching   vibrational mode observed by IR at 1170cm-1.  2) The IR of   Ag(NH3)ClO4 has three Cl-O  stretching vibrational modes at 1220 cm-1,1130 cm-1and 920 cm-1 observed in the IR .

Question

Provide explanations for the number of intense perchlorate Cl-O stretching vibrational modes observed in the IR of the following three silver(I) complexes.  explain briefly 

1) The perchlorate anion in Ag(NH3)2(ClO4) has a single intense Cl-O stretching   vibrational mode observed by IR at 1170cm-1

2) The IR of   Ag(NH3)ClO4 has three Cl-O  stretching vibrational modes at 1220 cm-1,1130 cm-1and 920 cm-1 observed in the IR .     

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