Some different views of an octahedral symmetry metal complex1313632 1422View down a C, axisView down a C, axisView down a C, axisOnE 8C36C2 6C, 3C,i 6S, 8S, 30, 604A1g111111111-1-11Azg1-11-1z², x² - y?Eg2-1-1Tig-1-1-11-1T2g(xy, xz, yz)1-1-1-1-1A1u-1-1-1-1111-1A2u11-1-1-1-1-11E-1-21-23-11-1-3-1(x, y, z)3Tzu-1-1-311-1The octahedral character table above may be useful for the following questions.1.1.2.3.3.2.3.3.1.2. Using octahedral symmetry, match each ligand SALC with its most likely interaction with a metawithin the Lewis acid/base model.(The Generic Octahedral Metal Complex information above may be useful in doing this.)Eg symmetry SALC (ligand = NH3)V[ChoosPi BaseSigma BaseEg symmetry SALC (ligand = 1-)Pi AcidSigma AcidT2g symmetry SALC (ligand = 1-)[ Choose ]T2g symmetry SALC (ligand = CO)%3D[ Choose ]>

There are two types of ligand π acceptor or π acid ligand and sigma donar ya sigma base ligand. The…

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Some different views of an octahedral symmetry metal com

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 53AP

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Question

Some different views of an octahedral symmetry metal complex
1
3
1
3
6
3
2 1
4
2
2
View down a C, axis
View down a C, axis
View down a C, axis
On
E 8C3
6C2 6C, 3C,
i 6S, 8S, 30, 604
A1g
1
1
1
1
1
1
1
1
1
-1
-1
1
Azg
1
-1
1
-1
z², x² - y?
Eg
2
-1
-1
Tig
-1
-1
-1
1
-1
T2g
(xy, xz, yz)
1
-1
-1
-1
-1
A1u
-1
-1
-1
-1
1
1
1
-1
A2u
1
1
-1
-1
-1
-1
-1
1
E
-1
-2
1
-2
3
-1
1
-1
-3
-1
(x, y, z)
3
Tzu
-1
-1
-3
1
1
-1
The octahedral character table above may be useful for the following questions.
1.
1.
2.
3.
3.
2.
3.
3.
1.
2.

Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta
within the Lewis acid/base model.
(The Generic Octahedral Metal Complex information above may be useful in doing this.)
Eg symmetry SALC (ligand = NH3)
V[Choos
Pi Base
Sigma Base
Eg symmetry SALC (ligand = 1-)
Pi Acid
Sigma Acid
T2g symmetry SALC (ligand = 1-)
[ Choose ]
T2g symmetry SALC (ligand = CO)
%3D
[ Choose ]
>

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