-С—СНз *MgBr CH3CH2-MgBr CH3- a. CH3 `CH3 CH2CH3 CH;CH,CH> — ОСНЗ b. CH3CH2CH2-Br + CH3Ö: Brг CH3 CH3 CH3 CH3 :ö: :б d. CH3-C-OCH2CH3 CH;CH2O CH3 CH3 CH3

Q: CH2-C= C-CH3 CH 3-C=C-CH2-CH2- CH3 CH3-CH2- CH2- C = C -CH2-CH2-CH2- CH2-CH3

A: Select the parent chain Label the parent chain in such a way giving smaller number to alkynic carbon…

Q: (a) NaBH4 (CH3)2CHCH2CH2 CH CH3CH,OH (b)

A:

Q: Name the 3. CH=CCH,CH=CH, 10 er CH, 4. CH,CCH,C=CH CH, 5. CH,CH,CCH,CH, CH,

A: Naming of alkenes and alkynes is done by first identifying the longest chain of carbon atoms that…

Q: CH,O-C- CH2(CH2),CH3 b. CH2OH сно- -CH2(CH2),CH3 CHOH + 3 CH3(CH2),CH¿ċ–O'Na* CH,OH C. e. ČH2O-…

A: The above reaction is a hydrolysis of fatty acids. Fatty acids are prepared by esterification…

Q: H,C-CH-CH, ČH, H,C-CH-CH, ČH2-CH, H,C-CH,-CH2-CH-CH,-CH2-CH3 ČH;-CH, CH2-CH, H3C-CH2-CH2-CH-…

A:

Q: h) CH3-CH2-CH2-CH2- ċ=ċ-CH3 i) CH3 -CH3 CH3 CH3-CH,–ĊH ČH3 HIC

A:

Q: CH3 CH3 C-CH,CH3 CH3 CH3 CH3 CH3 CH,CH3 CH3 CH;CH-CH=CHCH,CH= CH, CU C UCHT

A: since you have posted multiple questions in a single session, we are entitiled to answer only first…

Q: Draw the products in each reaction.

A: NOTE: Since, we only answer upto three sub-parts, we'll answer the first 3. Please resubmit the…

Q: Give an acceptable name for each amine.

A: Amines are the chemical compounds which consists a nitrogen atom that is attached to aliphatic…

Q: CH3 CH,CH2-C-CH,CH2 f. CH3 CH3 CH,CH,CH2-C-CH3 ČH3

A:

Q: CH2-0-C-(CH2)4CH=CHCH,CH=CH(CH2); CH3 3 H2 CH-O-C-(CH2)4CH=CH(CH2)2CH3 Pt ČH2-0-C-(CH2)4CH3

A: Hydrogenation of lipids

Q: CH- CH3 CH2 NH NH Cystine unit сн — CH, — s—s—сH,— сH - NH NH 0=C CH, - CH,OH CH- CH CH `CH3 NH NH…

A: NH-C=O linkage is called peptide bond. S-S linkage is called disulphide linkage. The general form of…

Q: 1. CH3-C=CH2 CH3-CHz- CH CH; 2. CH3 - CH2 - C=CCH2 -CH; 3. (CH:),CHC CCH(CH3)2

A: Note: Since you have posted a  question with sub-parts , we are entitled to answer the first three…

Q: 12. CI 11. CI, Br c=C CH2=Ċ-CH=CH, CH3 CH2CH2CH3 Br 13. CH3-CH-CH2–CH=CH2

A: Since you have asked questions with multiple subparts we will solve the first three subparts for…

Q: CH3 AICI3 + CH2-CH-CH2-CI CH3 CH3 -CH2-CH-CH3 .CH-CH2-CH3 (а) (b) CH3 CH3 -CH3 CH2-CH2-CH2…

A:

Q: The structural formula for (CH3),C(CH;CH;);is CH;CH;CCH;CH;CH;CH3 a. b. CH;CH,CH;=CH;CH;CH; H2 C-CH3…

A: Correct answer is (d).  Given compound is 3,3-dimethylpentane.

Q: Give the IUPAC name for each thiol.

A: IUPAC names : (a) Pentan-3-thiol   (b) Cyclohexanethiol   (c) 5-ethylheptan-1-thiol

Q: CH;CH2- N-CH,CH3 + HCl - (21) CH,CH3 (22) || ethanol H;C-C- CH=CH, + HN(CH,CH3)2 CI (23) Br 1. ΗΝΟ ,…

A:

Q: CH3 CH3-C-CH2-CH-CH2-CH3 &CH3)3 CH3 1. ÇH3 CH2=C-CH=CH2 CH3 CH3-CH=CH-C=C-CH ČH3 2. 3.

A: The IUPAC name of an alkane consists of three parts: rootname, prefix and suffix. The carbon atom…

Q: CH3 AICI3 + CH2-CH-CH2-CI CH3 CH3 CH2-CH-CH3 .ĊH-CH2-CH3 (а) (b) CH3 CH3 -CH3 CH2-CH2-CH2…

A:

Q: CH3 CH3-CH2-C-CH2-C-CH2CH3 ČH3 b) c) CH3 CH3-CH2-C HO- | CH3 d) CH3 CH3 он CH3 CH3-C-OH…

A:

Q: H* H3C-C-0-CH2CH3 H,0 H" 0-H + H,C. H,C HN +

A: The reaction in which and acid reacts with an alcohol to produce an ester is called esterification.…

Q: CH3 CH3-C-CH-CH2-CH3 ÔH3 CH2-CH3 CH3 CH3-CH-CH-CH-CH3 CH3 CH2-CH3 CH3 CH3-CH-C-CH2-CH2-CH3 CH3…

A: We have given the structure of following alkanes compound.The IUPAC name of these compounds…

Q: H20, H2SO, (h) H&SO, (i) CH3-C=c-CH3 + H2 Lindlar CH3OH B H2SO, Br2 (6) CH,-CH=CH-CH, 2NANH, B

A: Since you have posted a question with multiple sub-parts, we will solve first three sub-parts for…

Q: OH -CH2CH3 CH3 (a) 1. CH3M9CI, then H3O* 2. (CH3CH2)2CuLi, then H3O* (b) 1. (CH3CH2)2CULI, then H3O*…

A: In this problem we will use the following two reagents: Grignard reagent (RMgX)-There are also…

Q: (c) C6H5-C-CH2–CH3 and C3H5–CH2–Ċ–CH3 CH3 CHaC_ÇH–CH2–CH3 and CH3–C–CH2–CH–CH3 8 ČH3

A:

Q: What stereoisomers would you expect to obtain from each of the following reactions?

A:

Q: (g) NH + CH3(CH2)6CH,CI ethanol (h) -CH2CI + NH3 ethanol

A:

Q: Give the correct iupac name for the following compounds

A: According to IUPAC Nomenclature, the name of the compound is written as  Prefix + Root word + 1°…

Q: 12, CCI4 CH2-0-C-(CH2)7-CH=CH-(CH2)5CH3 H2, Pt CH-O-C-(CH2)16CH3 3 NaОH ČH2-0-C-(CH2)14CH3 H30*

A: The given reactions are :

Q: CH3 ●• Mg :ÕH :0: || CI CH3-CH,-C-CH3 CH3-CH,-C-CH3 2 H* CH3 :0: || CH3-CH2-C-CH3 CH3-CH,-C-CH3 OCH3…

A: Carbonyl compounds reacts with alkylated magnesium halides (Grignard reagent) and undergo…

Q: CI CI CH3- CH CH2 CH CH2 - CH2 C2H5

A:

Q: 6 CH3(CH2)9CHCH2 7 CH3(CH2)9CCH 1 CH3 H3C-C-0-CH3 8 Straight chain C6H10 CH3 CH3CCH(CH2)16CH3 10…

A: Given compounds are :  Identify Alkene, alkyne, alcohol or ether = ?

Q: CH3 CH3-C-CH2-CH-CH2-CH3 CH3 C(CH3)3 1. CH3 CH2=ċ-CH=CH2 CH3 CH3-CH=CH-C=c-CH CH3 3. 4.…

A: The Lewis structures and 3D molecular model is drawn. Note that sp³ carbons have an bond angle of…

Q: CH3-CH2-CH2-C(CH3)=CH-CH2-CH2-C(CH3)3

A:

Q: ÇI j. Br-C-CH2-ĆH-CH3 Туре of functional group CI Br- CH,-CH-CH, IUPAC CI Br-C-CH2-CH-CH3 Common…

A: The question is based on the concept of IUPAC naming and common naming. there are certain rules to…

Q: CH3-o CH2-CH2-CH2.-Ct3 CH8 -CH-CH20-CH2-C H3 CH3-C Hz-0-CHz-CH 2 -Cto CH3-0-CH - CH 2-CH3 (F 0-CH3…

A:

Q: CH3 :C CH3 H3C-CH2 CH3 CH3 CH,CH3 ČH,CH3

A:

Q: name the compounds systematically CH3 (a) CH3CH2 CH,CHCH,CH3 H CH,CH3 (c) HC CCHĊCH3 ČH3 (d)…

A:

Q: Are the following compounds belong to the same homologous series? Η Η Η Η Η Η Η OH H |||||…

A: The chemical properties of an organic molecule depend mostly on the functional group. Different…

Q: CH2CH3 CH,CH3 CH2 CH,CH3 CH2CH3 CH,CH3 CH2CH3 CH,CH3

A: We know heat of hydrogenation of alkene is inversely proportional to stability of alkene. Heat of…

Q: a. CH;(CH2)4I, CH3(CH2)5I, CH3(CH2)çI b. CH3CH¿CH;NH2, (CH3);N, CH3CH¿CH,CH3 c. (CH3);COC(CH)a,…

A: Boiling point of a chemical compound is the temperature at which vapor pressure of a compound…

Q: (а) CH3 (b) + H3C. CH3 (с) CH3 H3C. (d) CH3 (е) H3C. CH3 + + + +

A: One of the given reactant is a conjugated diene and the other is dienophile (substituted alkene).…

Q: dentify the functional groups in the 1. CH3 - CH2 – CH, - OH 2. H-C C-CH2 - CH3 3. CH,CH2 - O- CH3…

A:

Q: Draw curved arrows to show the movement of the electrons as one (or more)bond breaks and another…

A: a. Carbon-carbon π bond undergoes homolytic cleavage. Among the two electrons of carbon carbon π…

Q: CH3 CH3 CH3 (а) CH3-C-CH-CH2-CH3 CH3-C-CH2-CH-CH3 H I or II CH3 CH3 (b) CH3-C-CH2-C=CH2 CH3-C…

A: We have to choose most stable species in given options.

Q: CH2-CH-CH=C-CH2, CH₂ CH3-CH2-CH-OH CH3-CH2-CH2 OH OH CH, CCH, CH, CH3 H₂SO4 140C KMnO₂ H₂SO4 180C…

A: We have to give the IUPAC name of the products of the given reactions.

Q: CH3 C나3CH CH2CO2H 1.) Brz

A: When 3-methylbutanoic acid is treated with Bromine in presence of phosphorus tribromide then…

Q: 3 ÇH3 CH3 CH3 CH3 CH,-c -H CH,-C-OH; CH;-C +:OH2 ČH; CH3-C CH;=C ČH3 ČH; CH; 2 CH3 CH;-C-CHCH, Hi…

A: In 2, there is no loss of H+, number of hydrogen in reactant and product are same.

Q: CH3 CH3 CH3 NaOCH3 CH2CH3 HC CH2CH3 CH,0C CH2CH3 Br SN2 H VwX XwV

A: SN2 reaction is a bimolecular nucleophic substitution reaction wherein the bond breaking and bond…

Reactive Intermediates

In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.

Hydride Shift

A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.

Vinylic Carbocation

A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.

Cycloheptatrienyl Cation

It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.

Stability of Vinyl Carbocation

Carbocations are positively charged carbon atoms.  It is also known as a carbonium ion.