Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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The compounds Br2 and ICI have the same number of electrons, yet Br2 melts at -7.2C, whereas ICI melts ar 27.3C. Explain.

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  • The molar heat of fusion of sodium metal is 2.60 kJ/mol, whereas its heat of vaporization is 97.0 kJ/mol. a. Why is the heat of vaporization so much larger than the heat of fusion? b. What quantity of heat would be needed to melt 1.00 g sodium at its normal melting point? c. What quantity of heat would be needed to vaporize 1.00 g sodium at its normal boiling point? d. What quantity of heat would be evolved if 1.00 g sodium vapor condensed at its normal boiling point?
    8.48 Why must the vapor pressure of a substance be measured only after dynamic equilibrium is established?
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  • Water at 0C was placed in a dish inside a vessel maintained at low pressure by a vacuum pump. After a quantity of water had evaporated, the remainder froze. If 9.31 g of ice at 0C was obtained, how much liquid water must have evaporated? The heat of fusion of water is 6.01 kJ/mol and its heat of vaporization is 44.9 kJ/mol at 0C.
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