The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128>s at 150 K.a. What is the half-life of the desorption reaction?b. If the surface is initially completely covered with n-butane at 150 K, how long will it take for 25% of the molecules to desorb (leave the surface)? For 50% to desorb?c. If the surface is initially completely covered, what fraction will remain covered after 10 s? After 20 s?
The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128>s at 150 K.a. What is the half-life of the desorption reaction?b. If the surface is initially completely covered with n-butane at 150 K, how long will it take for 25% of the molecules to desorb (leave the surface)? For 50% to desorb?c. If the surface is initially completely covered, what fraction will remain covered after 10 s? After 20 s?
Chapter13: Kinetic Methods
Section: Chapter Questions
Problem 3P
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The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128>s at 150 K.
a. What is the half-life of the desorption reaction?
b. If the surface is initially completely covered with n-butane at 150 K, how long will it take for 25% of the molecules to desorb (leave the surface)? For 50% to desorb?
c. If the surface is initially completely covered, what fraction will remain covered after 10 s? After 20 s?
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