The figure below shows TEM micrograph of a rubber toughened polystyrene (PS) orthotic (i.e. rubber particles were added to increase the toughness of the PS. The rubber particles are indicated by arrows. These rubber particles promote the formation of crazes which absorb energy, leading to a material with higher impact resistance. The rubber, which has a Tg of -60°C, can decrease the Tg of the PS (which has a Tg of 100C), however. Assume that the initial Tg of the PS is 80°C. How much would the Tg decrease if 40 weight percent of the rubber was added to PS? b. Sketch dsc curves of the initial PS before and after addition of the rubber.

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Chapter1: Chemical Foundations
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The figure below shows TEM micrograph of a
rubber toughened polystyrene (PS) orthotic (i.e.
rubber particles were added to increase the
toughness of the PS.
The rubber particles are indicated by arrows. These
rubber particles promote the formation of crazes
which absorb energy, leading to a material with
higher impact resistance. The rubber, which has a
Tg of -60°C, can decrease the Tg of the PS (which
has a Tg of 100C), however.
Assume that the initial Tg of the PS is 80°C. How
much would the Tg decrease if 40 weight percent of
the rubber was added to PS?
b. Sketch dsc curves of the initial PS before and after
addition of the rubber.
Transcribed Image Text:The figure below shows TEM micrograph of a rubber toughened polystyrene (PS) orthotic (i.e. rubber particles were added to increase the toughness of the PS. The rubber particles are indicated by arrows. These rubber particles promote the formation of crazes which absorb energy, leading to a material with higher impact resistance. The rubber, which has a Tg of -60°C, can decrease the Tg of the PS (which has a Tg of 100C), however. Assume that the initial Tg of the PS is 80°C. How much would the Tg decrease if 40 weight percent of the rubber was added to PS? b. Sketch dsc curves of the initial PS before and after addition of the rubber.
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