The following properties of a sample collected from a lake are measured: pH = 10.24 & carbonate concentration of 120 mg/L as CaCO3. What is the quantity of bicarbonate (in mg/L as CaCO3)? Given: K1 = 1063 & K2 = 10103 for the following %3D carbonate buffer system: CO2le) 2 H,CO;*2+ HCO, HCO, 2H+ Co,
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- One gram of sodium hydroxide (NaOH) is used to adjust the pH of an aqueous solution (200 gallons) thatcontains 10 lbs of finely ground rhodochrosite (MnCO3) ore. Does the NaOH raise or lower the solutionpH? What is the amount of NaOH added in lbs/ton? What is the molarity (mol/l) of the system? Assumingthe NaOH is completely soluble and the system is at room temperature, what is the solid-to-liquid ratio(wt%) of the system?The concentration of Cl– in a 300.0-mL sample of water drawn from a fresh water acquifer suffering from encroachment of sea water, was determined by titrating with 0.0516 M Hg(NO3)2. The sample was acidified and titrated to the diphenylcarbazone end point, requiring 6.18 mL of the titrant. Report the concentration of Cl–in parts per millionCalcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)
- 1) For an open system with PCO2=10−3.5 atm what fraction of the total carbonate is in the form of CO32− at pH 10.63? 2) Using paleolimnological methods it is possible to estimate past pH values of surface waters. If the estimate of pH is 5.787 , what is the corresponding PCO2? in atm.You have performed an iodimetric titration using a commercial vitamin C tablet. Based on the following information below, calculate the %(w/w) of vitamin C(MM=176.16 g/mol) in the tablet: Mass of tablet dissolved in 250.0 mL: 5.422 g Aliquot volume of sample titrated: 25.00 mL Concentration of KIO3: 0.023 M Final burrette volume: 41.31 mL Initial burrette volume: 8.89 mL Blank volume: 0.14 mLIn the standardi zation of HCl using pure anhydrou s sodium carbonate as primarystandard for methy l orange as indica tor , 1.0 mL HCl was found to be equiva lent to 0.05gof sodium carbonate (MW =106). The no rmality of HCl is
- For water having a total alkalinity of 1.00x10^-3 mol/L and a pH of 10.34 what is the percentage contribution to alkalinity from CO32-? Please answer very soon will give rating surelyWhen a drop (taken to be 0.20 cm3) of 1.0 M HCI(aq) is added to 25 cm3 of pure water, the resulting hydroniumion concentration rises to 0.0080 mol dm- 3 and so the pH changes from 7.0 t o 2.1, a big change. Now suppose the drop is added to 25 cm3 of an ethanoate buffer solution that is 0.040 MNaCH3CO2(aq) and 0.080 M CH3COOH(aq). What will be the change in pH?1. 1093-g sample of impure Na2CO3 was analyzed by residual precipitimetry. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back-titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the endpoint. The percentage Na2CO3 (MW = 106.0 g/mole) in the tested sample is ________ % ? Note: Express final answer using least number of significant figures. 2. The alkalinity of natural waters is usually controlled by OH- (MW = 17.01 g/mole), CO3-2 (MW = 60.01 g/mole), and HCO3- (MW = 61.01 g/mole), which may be present singularly or in combination. Titrating a 10.0-mL sample to a phenolphthalein endpoint requires 38.12 mL of a 0.5812 M solution of HCl, and an additional 18.67 mL of the same titrant to reach the methyl orange endpoint. The composition of the sample is _________% CO3-2 and ___________ % OH- Note: Express final answers using least number of significant figures.
- If 1.000 ml. of a solution of KMn04 is equiva- lent to 0.1000 millimole of NaCHO2 (sodium formate) in the fol- lowing titration: 3CHO2- + 2MnO- + H2O -> 3CO2 + 2MnO2 + 5OH-, what is the value of the KMnO4 in terms of grams of CaO in the volumetric method for calcium in which that element is precipitated as CaC2 4 .H2O and the precipitate is filtered, dis- solved in dilute H2S04 , and the oxalate titrated with permanganate?The protein content of wheat flour can be determined reasonably accurately by multiplying the percentage of nitrogen present by 5.7. A 2.06-g sample of flour was taken through a Kjeldahl procedure and the ammonia produced was distilled into a boric acid solution. If this solution required 34.70 mL of 0.174 N HCl for titration to the methyl red end point, what is the a) % Nitrogen and b) % protein in the flour? (Use 1:1 stoich ratio between N and HCl)The SO2 present in air is mainly responsible for the phenomenon of acid rain. The concentration of SO2 can be determined by titrating against a standard permanganate solution as follows: 5SO2 + 2MnO4- + 2H2O ---> 5SO42- + 2Ms2 + 4H+ Calculate the number of grams of SO2 in a sample of air if 4.90mL of 0.00700M KMnO4 solution are required for the titration. Be sure your answer has the correct number of significant digits.
