The heat capacity at 1 atm. pressure of solid magnesium in the temperature range from 0 oC to 560 oC, is given by the expression:         Cp = 6.20 + 1.33 x 10-3 T + 6.78 x 104 T-2 Cal. deg.-1 g. atom.-1 What is the increase of entropy per g. atom, for an increase of temperature from 300 K to 800 K at 1 atm. pressure?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
Section: Chapter Questions
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  1. The heat capacity at 1 atm. pressure of solid magnesium in the temperature range from 0 oC to 560 oC, is given by the expression:

        Cp = 6.20 + 1.33 x 10-3 T + 6.78 x 104 T-2 Cal. deg.-1 g. atom.-1

What is the increase of entropy per g. atom, for an increase of temperature from 300 K to 800 K at 1 atm. pressure?

 

2. Nitrogen trioxide dissociation according to the reaction.

When one mole of N2O3(g) is held at 25oC and 1 bar total pressure until equilibrium is reached, the extent of reaction is 0.30 what is ΔGo for this reaction at 25oC?

3 a) Why is not feasible in water? What would happen if we tried to make such a solution by mixing of KOH with

HCl?

 

b) Calculate the pH of a buffer that is 0.020 M in NH3 and 0.030 M in NH4Cl. What is the pH after adding 1.00 mL of 0.01 M NaOH to 0.10 L of this buffer?

  [Ka for NH4+ if 5.70 x 10-10]

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