The Ostwald process for the commercial production of nitric acid involves three steps: 4 NH3(g) + 5 O2(g) ® 4 NO(g) + 6 H2O(g) 2 NO(g) + O2(g) ® 2 NO2(g) 3 NO2(g) + H2O(l) ® 2 HNO3(aq) + NO(g) A. Calculate the ΔH°, ΔS°, ΔG°, and K (at 298 K) for each of the three steps in the Ostwald process. B. Calculate the temperature at which equilibrium happens for the first step. Is the temperature low or high? Why? C. Calculate the equilibrium constant for the temperature calculated in b + 50 degrees.
The Ostwald process for the commercial production of nitric acid involves three steps: 4 NH3(g) + 5 O2(g) ® 4 NO(g) + 6 H2O(g) 2 NO(g) + O2(g) ® 2 NO2(g) 3 NO2(g) + H2O(l) ® 2 HNO3(aq) + NO(g) A. Calculate the ΔH°, ΔS°, ΔG°, and K (at 298 K) for each of the three steps in the Ostwald process. B. Calculate the temperature at which equilibrium happens for the first step. Is the temperature low or high? Why? C. Calculate the equilibrium constant for the temperature calculated in b + 50 degrees.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section: Chapter Questions
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The Ostwald process for the commercial production of nitric acid involves three steps:
4 NH3(g) + 5 O2(g) ® 4 NO(g) + 6 H2O(g)
2 NO(g) + O2(g) ® 2 NO2(g)
3 NO2(g) + H2O(l) ® 2 HNO3(aq) + NO(g)
A. Calculate the ΔH°, ΔS°, ΔG°, and K (at 298 K) for each of the three steps in the Ostwald process.
B. Calculate the temperature at which equilibrium happens for the first step. Is the temperature low or high? Why?
C. Calculate the equilibrium constant for the temperature calculated in b + 50 degrees.
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