TReview Topics [Rererences Use the References to access important values if needed for this question. Furnace O absorber CO, absorber Sample A 10.08 gram sample of an organic compound containing C, H and O is analyzed by combustion analysis and 14.30 grams of CO, and S.782 grams of H,0 are produced. In a separate experiment, the molar mass is found to be 62.07 g mol. Determine the empirical formula and the molecular formula of the organic compound. Enter the elements in the order C, H. O empirical formula = molecular formula = Previous

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter3: Equation, The Mole, And Chemical Formulas
Section: Chapter Questions
Problem 3.85QE: A chemist prepared a compound that she thought had the formula FeI3. When the compound was analyzed,...
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TReview Topics
[Rererences
Use the References to access important values if needed for this question.
Furnace
O absorber
CO, absorber
Sample
A 10.08 gram sample of an organic compound containing C, H and O is analyzed by combustion analysis and 14.30 grams of CO, and
S.782 grams of H,0 are produced.
In a separate experiment, the molar mass is found to be 62.07 g mol. Determine the empirical formula and the molecular formula of the
organic compound.
Enter the elements in the order C, H. O
empirical formula =
molecular formula =
Previous
Transcribed Image Text:TReview Topics [Rererences Use the References to access important values if needed for this question. Furnace O absorber CO, absorber Sample A 10.08 gram sample of an organic compound containing C, H and O is analyzed by combustion analysis and 14.30 grams of CO, and S.782 grams of H,0 are produced. In a separate experiment, the molar mass is found to be 62.07 g mol. Determine the empirical formula and the molecular formula of the organic compound. Enter the elements in the order C, H. O empirical formula = molecular formula = Previous
Expert Solution
Step 1

Moles of compound combusted = mass of compound / molar mass of compound = 10.08 / 62.07 = 0.1624 approx

Assuming the molecular formula of compound is CaHbOc 

Hence moles of C present in 10.08 grams of compound = moles of compound X a = 0.1624a

And moles of H present in 10.08 grams of compound = moles of compound X b = 0.1624b

And moles of O present in 10.08 grams of compound = moles of compound X c = 0.1624c

 

Step 2

Since the moles of C present in compound should be equal to the moles of CO2 forming as the moles of carbon should be same

Since moles of CO2 forming = mass / molar mass = 14.3 / 44 = 0.325 = moles of C in the compound 

Hence 0.1624 a = 0.325 

=> a = 2 

And since each mole of H2O has 2 mole of H and also the moles of H in compound should be equal to the moles of H in H2

hence the moles of H = moles of H2O X 2 = 8.782 X 2 / 18 = 0.976 

Hence moles of H in compound = 0.1624 b = 0.976 => b = 6 

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