Twenty dietary iron tablets with a total mass of 22.131 g were ground and mixed thoroughly. Then 2.998 g of the powder were dissolved in HNO3 and heated to convert all the iron to Fe31. Addition of NH3 precipitated Fe2O3 ? xH2O, which was ignited to give 0.264 g of Fe2O3 (FM 159.69). What is the average mass of FeSO4 ? 7H2O (FM 278.01) in each tablet?

Twenty dietary iron tablets with a total mass of 22.131 g were ground and mixed thoroughly. Then 2.998 g of the powder were dissolved in HNO3 and heated to convert all the iron to Fe31. Addition of NH3 precipitated Fe2O3 ? xH2O, which was ignited to give 0.264 g of Fe2O3 (FM 159.69). What is the average mass of FeSO4 ? 7H2O (FM 278.01) in each tablet?

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter11: Atomic Mass Spectrometry

Section: Chapter Questions

Problem 11.10QAP

See similar textbooks

Similar questions

A sample of anhydrous Na2CO3 (FM = 105.989) is suspected to be contaminated with eitherNaHCO3 (FM = 84.007) or NaOH (FM = 39.997) To verify the suspicion, a 0.7483 g sample was dissolved to prepare a 50.00 mL solution, and a 10.00 mL aliquot was taken to prepare a 100 mL solution, where 25.00 mL was analyzed using single flask method. If the sample requires 27.50 mL of standard 0.0125 N HCl to reach the phenolphthalein endpoint and another 28.40 mL to reach the bromcresol green endpoint, calculate the percentagecomposition (in %w/w) of all the basic components in the sample.
A sample of anhydrous Na2CO3 (FM = 105.989) is suspected to be contaminated with either NaHCO3 (FM = 84.007) or NaOH (FM = 39.997) To verify the suspicion, a 0.7483 g sample was dissolved to prepare a 50.00 mL solution, and a 10.00 mL aliquot was taken to prepare a 100 mL solution, where 25.00 mL was analyzed using single flask method. If the sample requires 27.50 mL of standard 0.0125 N HCl to reach the phenolphthalein endpoint and another 28.40 mL to reach the bromcresol green endpoint, calculate the percentage composition (in %w/w) of all the basic components in the sample.
Two analysts each made six determinations of the paracetamol content of the same batch of tablets. The results are shown below:Analyst Paracetamol content % (m/m)A 84.32 84.51 84.63 84.61 84.64 84.51B 84.24 84.25 84.41 84.13 84.00 84.30 How many moles of the analyte P is gravimetrically equivalent to P2O5?A) 1B) 2C) 3D) 4E) 5
Consider the titration illustrated in Figure 8.] Anhydrous sodium carbonate (Na₂CO₃) is a primary standard. When 0.364 grams of the substance is placed in a conical flask, then 20.00 cm³ of sulphuric acid (H₂SO₄) solution is required to reach the end point of the titration. What is the concentration in mol·dm⁻³ of the sulphuric acid solution? [Give the answer to 3 decimal places. Do not type in the unit. Use a decimal point.] *
A sample containing iron is approximately 99.0% w/w Fe. Using ammonia, iron is precipitated as Fe (OH)3 which is ignited to Fe203. (a) What is the gravimetric factor for analyte Fe (AW=55.85 g/mol) and precipitate Fe203 (FW=159.69 g/mol)? (b) What mass of sample is needed to ensure that the Fe203 precipitate would weigh at least 1.00 g?
A 25 mL liquid bleach sample is diluted with water to 1000 mL in a bubble gel. 25 mL of the diluted sample is transferred to the flask with a pipette, excess KI is added to it, and thus OCl- ion turns into Cl- ion and I2 is formed. The released iodine is titrated with 0.09892 Na2S2O3 using the starch reagent, and 8.96 mL is required for the endpoint. Find the % NaOCl (w/v; w/v) in the bleach sample. (Na=23 g/mol, O= 16 g/mol, Cl = 35.44 g/mol) (Warning: solving the necessary reaction equations by writing is necessary to see the stoichiometric relationship)
A sample of anhydrous NaHCO3 (FM = 84.007) is suspected to be contaminated with either NaOH (FM = 39.997) or Na2CO3 (FM = 105.989). To verify the suspicion, a 0.7483 g sample was dissolved to prepare a 50.00 mL solution, and a 10.00 mL aliquot was taken to prepare a 100 mL solution, where 25.00 mL was analyzed using double flask method. If the sample requires 0.45 mL of standard 0.0125 N HCl to reach the phenolphthalein endpoint and 35.95 mL to reach the bromcresol green endpoint, calculate the percentage composition (in %w/w) of all the basic components in the sample.
An impure sample of Na3PO3 weighing 0.1392 g was dissolved in 25 mL of water. A solution containing 50 mL of 3% w/v mercury(II) chloride, 20 mL of 10% w/v sodium acetate, and 5 mL of glacial acetic acid was then prepared. The solution containing the phosphite was added dropwise to the second solution, oxidizing PO3^3– to PO4^3– and precipitating Hg2Cl2. After digesting, filtering, and rinsing, the precipitated Hg2Cl2 was found to weigh 0.4320 g. Report the purity of the original sample as %w/w Na3PO3. Moles Na3PO3 = moles Hg2Cl2
4) How would your calculated value of Kup be affected by errors introduced from the following sources? Be specific in your answer. State whether Ksp would be too large, too small, or not affected, and explain why that error would have that effect on Ksp c. Although the KIOs used to standardize the Na2S20s is labeled as 0.0100 M, its actual concentration is somewhat higher than 0.0100 M. d. Extraneous water is introduced from wet filter paper or wet funnels, or by washing the precipitate during the final filtration of Ca(IOs)2.
A 25 mL liquid bleach sample is diluted with water to 1000 mL in a bubble gel. 25 mL of the diluted sample is transferred to the flask with a pipette, excess KI is added to it, and thus OCl- ion turns into Cl- ion and I2 is formed. The released iodine is titrated with 0.09892 M Na2S2O3 using the starch reagent, and 8.96 mL is required for the endpoint. Find the % NaOCl (w/v; w/v) in the bleach sample. (Na=23 g/mol, O= 16 g/mol, Cl = 35.44 g/mol) (Warning: solving the necessary reaction equations by writing is necessary to see the stoichiometric relationship) A. 0.132% B. 0.264% C. 5.28% D. 10.56%
A weight of 0.50 g was taken impure container containing sodium carbonate and bicarbonate. Dissolved in water and then crushed with hydrochloric acid (0.1 N), the burette reading game was at the endpoint of phenolphthalein of 10.5 ml and at the end point of the orange methylation point 30.1 ml. The percentage of sodium carbonate was in ................. knowing that the weights are: Na: 23, C: 12, O: 16
A sample of anhydrous NaHCO3 (FM = 84.007) is suspected to be contaminated with eitherNaOH (FM = 39.997) or Na2CO3 (FM = 105.989). To verify the suspicion, a 0.7483 g sample was dissolved to prepare a 50.00 mL solution, and a 10.00 mL aliquot was taken to prepare a 100 mL solution, where 25.00 mL was analyzed using double flask method. If the sample requires 0.45 mL of standard 0.0125 N HCl to reach the phenolphthalein endpoint and 35.95 mL to reach the bromcresol green endpoint, calculate the percentage composition (in %w/w) of all the basic components in the sample.