Using standard heats of formation, calculate the standard enthalpy change for the following reaction.2H2S(g) +302(g)^2H20(g) + 2S02(g)ANSWER:kJ

The exchange of heat between the system and the surrounding is equal to the change in enthalpy of…

Answered: Using standard heats of formation,…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter5: Thermochemistry

Section: Chapter Questions

Problem 5.27QE

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Sodium carbonate, Na2CO3, is used to manufacture glass. It is obtained from sodium hydrogen carbonate, NaHCO3, by heating. 2NaHCO3(s)Na2CO3(s)+H2O(g)+CO2(g) Calculate the standard enthalpy of reaction, using enthalpies of formation (Table 6.2).
Write an appropriate thermochemical expression in each case. (You may need to use fractional coefficients.) (a) The standard formation enthalpy of NH3(g) at 25 C is 46.11 kJ/mol. (b) The standard formation enthalpy of CO(g) at 25 C is 110.525 kJ/mol.
Chlorine trifluoride is a toxic, intensely reactive gas. It was used in World War II to make incendiary bombs. It reacts with ammonia and forms nitrogen, chlorine, and hydrogen fluoride gases. When two moles of chlorine trifluoride react, 1196 kJ of heat are evolved. (a) Write a thermochemical equation for the reaction. (b) What is Hf for ClF3?
A 250-g sample of water at 20.0C is placed in a freezer that is held at a constant temperature of 20.0C. Considering the water as the system, answer the following questions: a What is the sign of qsys for the water after it is placed in the freezer? b After a few hours, what will be the state of the water? c How will the initial enthalpy for the water compare with the final enthalpy of the water after it has spent several hours in the freezer? d What will the temperature of the water be after several hours in the freezer?
Isooctane is a primary component of gasoline and gives gasoline its octane rating. Burning 1.00 mL of isooctane (d=0.688g/mL) releases 33.0 kJ of heat. When 10.00 mL of isooctane are burned in a bomb calorimeter, the temperature in the bomb and water rises from 23.2C to 66.5C. The bomb contains 1.00 kg of water. What is the heat capacity of the calorimeter?
The head of a strike anywhere match contains tetraphosphorus trisulfide, P4S3. In an experiment, a student burned this compound in an excess of oxygen and found that it evolved 3651 kJ of heat per mole of P4S3 at a constant pressure of 1 atm. She wrote the following thermochemical equation: P4S3(s)+8O2(g)P4O10(s)+3SO2(g);H=3651kJ Calculate the standard enthalpy of formation of P4S3, using this students result and the following standard enthalpies of formation: P4O10(s), 3009.9 kJ/mol; SO2(g), 296.8 kJ/mol. How does this value compare with the value given in Appendix C?
One of the components of jet engine fuel is n-dodecane, C12H26(), which has a standard enthalpy of combustion of 8080.1 kJ/mol. (a) Write the thermochemical equation for the combustion of n-dodecane. (b) Use the standard enthalpies of formation in Appendix G to calculate the standard enthalpy of formation of n-dodecane.
Ethylene glycol, HOCH2CH2OH, is used as antifreeze. It is produced from ethylene oxide, C2H4O, by the reaction C2H4O(g)+H2O(l)HOCH2CH2OH(l) Use Hesss law to obtain the enthalpy change for this reaction from the following enthalpy changes: 2C2H4O(g)+5O2(g)4CO2(g)+4H2O(l);H=2612.2kJHOCH2CH2OH(l)+52O2(g)2CO2(g)+3H2O(l);H=1189.8kJ
Another reaction that is used to propel rockets is N2O4(l)+2N2H4(l)3N2(g)+4H2O(g) This reaction has the advantage that neither product is toxic, so no dangerous pollution is released. When the reaction consumes 10.0 g liquid N2O4, it releases 124 kJ of heat. (a) Is the sign of the enthalpy change positive or negative? (b) What is the value of H for the chemical equation if it is understood to be written in molar quantities?
A sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is burned in a bomb calorimeter, sodium chloride does not burn. What is the percentage of sucrose in the sample if a temperature increase of 1.67C is observed when 3.000 g of the sample are burned in the calorimeter? Sucrose gives off 5.64103kJ/mol when burned. The heat capacity of the calorimeter and water is 22.51 kJ/C.
A bomb calorimetric experiment was run to determine the enthalpy of combustion of ethanol. The reaction is C2H5OH() + 3 O2(g) 2 CO2(g) + 3 H2O() The bomb had a heat capacity of 550 J/K, and the calorimeter contained 650 g of water. Burning 4.20 g of ethanol, C2HsOH() resulted in a rise in temperature from 18.5 C to 22.3 C. Calculate U for the combustion of ethanol, in kJ/mosl.
A 10.00-g sample of acetic acid, HC2H3O2, was burned in a bomb calorimeter in an excess of oxygen. HC2H3O2(l)+2O2(g)2CO2(g)+2H2O(l) The temperature of the calorimeter rose from 25.00C to 35.84C. If the heat capacity of the calorimeter and its contents is 13.43 kJ/C, what is the enthalpy change for the reaction?

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Using standard heats of formation, calculate the standard enthalpy change for the following reaction. 2H2S(g) +302(g)^2H20(g) + 2S02(g) ANSWER: kJ