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A: Yes, the reaction of s-2-bromobutane with sodium hydroxide will produce the racemic mixture.
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A: (a)
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Q: 1. CH3M9BR 2. H20
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Q: An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a…
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A: Both the structures have been drawn below.
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Q: Identify the coupling partners that can be used to prepare the following compounds in a Heck…
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What does Meso-dibromobutante on debromination gives?
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- After E2 elimination, will the following molecule contain deuterium? Why or why not?there are two benzylic bromides that give (z)-4,6-dimethyl-3-phenyl-3-heptene on E2 elimination. What would be the two structures?Solvolysis of 2-bromo-2-methylbutane in acetic acid containing sodium acetate gives three organic products. What are they?
- Nitration of nitrobenzene yields mainly the meta product. Please show why the sigma complex is lower in energy for substitution at meta position than it is for substitution at the ortho and para positions.Which of the following bases gives the highest Zaitsev product in an E2 reaction with 2-bromo-2,3-dimethylbutane?Grinard Reaction with Aldehyde: (a) What peaks in the NMR spectrum most clearly demonstrate the presence of the predicted product ,1-(4-methoxypenyl)-methylpropan-1-ol? (b) If the product had unreacted aldehyde remaining, what NMR peak would indicate the presence of this contaminant?
- Which of the hydrogens will be abstracted first when mono-brominating with Br2 and light?What is the purpose for all of the following ? Carry out an electrophilic aromatic substitution reaction Prepare methyl m-nitrobenzoate by the nitration of methyl benzoate Verify the identity of a product through infrared spectroscopyIn an aqueous solution containing sodium bicarbonate, aniline reacts quickly with bromine to give 2,4,6-tribromoaniline. Nitration of aniline requires very strong conditions, however, and the yields (mostly m-nitroaniline) are poor.Explain why nitration of aniline is so sluggish and why it gives mostly metasubstitution.
- The reaction of 1-bromoheptane with the propionate anion to give heptyl propionate ester is greatly accelerated by adding catalytic amounts of KI. Explain.How many distinct alkene products are possible when the alkyl iodide below undergoes E2 elimination?Suggest an explanation for the fact that the order of reactivity of the halides toward n-butylbrosylate in acetone is Cl” > Br” > I~ when (C4H9)4N* is the cation of the halide salt butI” > Br” > Cl” when Li’ is the cation