What hypothesis did the Hammond Postulate help us to craft regarding the stability of carbocations and first order reaction rates? If a first order reaction proceeds faster, then the carbocation intermediate is more stable. O If a first order reaction proceeds more slowly, then the carbocation intermediate is more stable. O If a reaction proceeds with first order kinetics, then the carbocation intermediate is more stable. O If a reaction proceeds with second order kinetics, then the carbocation intermediate is less stable. O If a reaction proceeds with first order kinetics, then the transition state must be less stable than the carbocation intermediate. O If a reaction proceeds with second order kinetics, then the transition state must be less stable than the carbocation intermediate.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 4E: Draw the complete mechanism of each pair of reactants including any favorable rearrangements and all...
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What hypothesis did the Hammond Postulate help us to craft regarding the stability of
carbocations and first order reaction rates?
If a first order reaction proceeds faster, then the carbocation intermediate is more stable.
O If a first order reaction proceeds more slowly, then the carbocation intermediate is more stable.
O If a reaction proceeds with first order kinetics, then the carbocation intermediate is more stable.
O If a reaction proceeds with second order kinetics, then the carbocation intermediate is less stable.
O If a reaction proceeds with first order kinetics, then the transition state must be less stable than
the carbocation intermediate.
O If a reaction proceeds with second order kinetics, then the transition state must be less stable than
the carbocation intermediate.
Transcribed Image Text:What hypothesis did the Hammond Postulate help us to craft regarding the stability of carbocations and first order reaction rates? If a first order reaction proceeds faster, then the carbocation intermediate is more stable. O If a first order reaction proceeds more slowly, then the carbocation intermediate is more stable. O If a reaction proceeds with first order kinetics, then the carbocation intermediate is more stable. O If a reaction proceeds with second order kinetics, then the carbocation intermediate is less stable. O If a reaction proceeds with first order kinetics, then the transition state must be less stable than the carbocation intermediate. O If a reaction proceeds with second order kinetics, then the transition state must be less stable than the carbocation intermediate.
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