Which compound will be a major product of the reaction sequence shown? NO2 NO2 (1) HNO 3/H,SO,, A SoH (2) H2S0/H0, A (3) SnCl/HCI CI NO2 NH2 C D Compound D Compound A Compound C Compound B
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- The product of reaction between acetone and bromine (excess) with KOH excess is A. Ch2BrCOCh3 B. ChBr3 C.ChBr2COCH3 D.CBr3COCH3 E.Ch2BrCOCHBr2select the most appropriate reagent(s) to effect the change. 1. Disiamylborane, 2. HO–, H2O, H2O2 H2, Pd K2Cr2O7, H+ NaOCl H2SO4, HgSO4Draw a stepwise mechanism for the attached reaction that illustrateshow two substitution products are formed. Explain why 1-bromohex-2-ene reacts rapidly with a weak nucleophile (CH3OH) under SN1 reactionconditions, even though it is a 1 ° alkyl halide.
- Draw the mechanism ffrom benzaldehyde to this using: i)NaBH4 ii)TsCl, py iii)NaCN iiii)H+, H2OBromide Bhas normal activity (for a secondary bromide) towards SN1 substitution, but A has much higher reactivity and Chas much lower reactivity.Supply the missing reagent in the following reaction: (see attachment) A. Lindlar, H2, mCPBA B. O3 or KMnO4 C. fused KOH D. NH3 E. NaNH2
- Please draw the mechanism (assuming an SN1pathway) for the reaction of cyclopentyl bromide with the cyanide anion (-CN) to yield cyclopentyl cyanide as the organic product Thank youWhat is the best way to remeber the differences between Sn1, Sn2, E1 and E2 reations?Draw the major product and state wheter the reaction is SN2, E2, SN1, or E1
- Identify F in the following reaction sequence. F was converted in several steps to the antidepressant paroxetine (trade name Paxil; see also Problem 9.9).Please label all the steps and reagents with their corresponding letter. Thanks!The anticoagulant Warfarin can be synthesized by a conjugate addition (Michael addition) reaction as shown below: a) Propose a mechanism for the reaction starting from the enolate shown below. You can assume water is present for any proton transfers needed.b) We saw that the keto tautomer is normally preferred over the enol tautomer, however, the enol tautomer is present in the final product (Warfarin) and that is the more stable tautomer in this case. Why do you think the enol tautomer is more stable? Hint: consider the molecule as a whole.