Which reactions will produce the desired product in good yield? You may assume thataluminum chloride is added as a catalyst in each case. For the reactions that will not givea good yield of the desired product, predict the major products.Reagents Desired Product(a) benzene + n-butyl bromide n-butylbenzene

Which reactions will produce the desired product in good yield? You may assume thataluminum chloride is added as a catalyst in each case. For the reactions that will not givea good yield of the desired product, predict the major products.Reagents Desired Product(a) benzene + n-butyl bromide n-butylbenzene

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.64P

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Which reactions will produce the desired product in good yield? You may assume thataluminum chloride is added as a catalyst in each case. For the reactions that will not givea good yield of the desired product, predict the major products.Reagents Desired Product(a) benzene + n-butyl bromide n-butylbenzene(b) ethylbenzene + tert-butyl chloride p-ethyl-tert-butylbenzene
Which reactions will produce the desired product in good yield? You may assume thataluminum chloride is added as a catalyst in each case. For the reactions that will not givea good yield of the desired product, predict the major products.Reagents Desired Product bromobenzene + ethyl chloride p-bromoethylbenzene
Starting with benzene and using any other necessary reagents of your choice, what are the possible syntheses for the following compound?
Starting from benzene, provide a synthesis of the following compound. Ensure that the product is prepared in the highest percent yield possible. Provide all necessary reagents and draw the compound formed after each step. You do not have to use curved arrows.
Which reactions will produce the desired product in good yield? You may assume that aluminum chloride is added as a catalyst in each case. For the reactions that will not give a good yield of the desired product, predict the major products. Reagents Desired Product(a) benzene + n-butyl bromide n-butylbenzene(b) ethylbenzene + tert-butyl chloride p-ethyl-tert-butylbenzene(c) bromobenzene + ethyl chloride p-bromoethylbenzene(d) benzamide (PhCONH2) + CH3CH2Cl p-ethylbenzamide(e) toluene + HNO3, H2SO4, heat 2,4,6-trinitrotoluene (TNT)
Isoprene has sometimes been used as a starting material in the laboratory synthesis of terpenes. In one such synthesis, the first step is the electrophilic addition of 2 mol of hydrogen bromide to isoprene to give 1,3-dibromo-3-methylbutane.Write a series of equations describing the mechanism of this reaction.
Write equations showing how to prepare each of the following from benzene or toluene and any necessary organic or inorganic reagents. If an ortho, para mixture is formed in any step of your synthesis, assume that you can separate the two isomers. (a) Isopropylbenzene (b) p-Isopropylbenzenesulfonic acid (c) 2-Bromo-2-phenylpropane (d) 4-tert-Butyl-2-nitrotoluene (e) m-Chloroacetophenone (f) p-Chloroacetophenone (g) 3-Bromo-4-methylacetophenone (h) 2-Bromo-4-ethyltoluene (i) 3-Bromo-5-nitrobenzoic acid (j) 2-Bromo-4-nitrobenzoic acid (k) 1-Phenyloctane (l) 1-Phenyl-1-octene (m) 1-Phenyl-1-octyne (n) 1,4-Di-tert-butyl-1,4-cyclohexadiene
Grignard reagent is a versatile tool in synthetic organic chemistry. Using bromocyclopentane as a starting material, show how a Grignard reagent, X, is synthesized. Reaction of X with water produces compound Y while treatment in carbon dioxide followed by hydrolysis forms compound Z. 3-methyl-2butanone reacts with X and hydrolyses to yield compound AA. Draw the structural formulae of compounds Y, Z and AA and write the chemical equations respectively.
The sex attractant of the housefly has the formula C23H46. When treated with warm potassium permanganate, this pheromone gives two products: CH3(CH2)12COOH and CH3(CH2)7COOH. Suggest a structure for this sex attractant. Explainwhich part of the structure is uncertain
Starting from bromobenzene and any other reagents and solvents you need, show how you would synthesize the followingcompounds. Any of these products may be used as starting materials in subsequent parts of this problem. 2-phenylbut-2-ene
A hydrocarbon (X), with the molecular formula: C8H14 is reduced in presence of sodium and liquid ammonia to give the only product (Y) with the molecular formula: C8H16. Compounds X and Y both resulting 2,5-dimethylhexane when treated with hydrogen and platinum catalyst (H2/Pt). As a result of the oxidative cleavage of compound Y (by using KMnO4 / H2SO4), a single carboxylic acid derivative with C4H8O2 molecular formula is formed. Again, as a result of the reaction of Y with perbenzoic acid, the chiral compound C8H14O is observed, but the reaction of compound Y with bromine gives the achiral C8H14Br2 as the product.
Suggest the most appropriate method for each of the following laboratory syntheses.(a) cyclopentanol ¡ cyclopentanone