Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 1, Problem 1.41E
Table 1.4 show that the second virial coefficient B for He is negative at low temperature, seems to maximize at a little over 12.0 cm3/mol, and then decreases. Do you think it will become negative again at higher temperatures? Why is it decreasing?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Use the virial equation of state to calculate the pressureexerted by 1.00 mol CH4, at 273 K confined to a volumeof 1.00 cm3, given the value of the second virial coefficient.B = -53.6 cm3 mol·'. at this temperature. You may assumethat the expansion may be truncated after the second term.
After studying the concept of real gases, Zainab was perplexed to know the following:(a) Why the term that corrects for volume, and pressure term is negative in van der Waals equation? (b) Further, why is n/V squared in the van der Waals equation?
It is desired to market O2 in small cylinders having volumes of 15L and each containing 2 kg of O2. If the cylinders may be subjected to a maximum temperature of 500C, calculate the pressure, for which they may be designed, assume the applicability of the ideal gas law.
Chapter 1 Solutions
Physical Chemistry
Ch. 1 - A bomb calorimeter is a study metal vessel in...Ch. 1 - Difference between the system and the...Ch. 1 - Prob. 1.3ECh. 1 - Prob. 1.4ECh. 1 - Prob. 1.5ECh. 1 - Prob. 1.6ECh. 1 - Prob. 1.7ECh. 1 - A pot of cold water is heated on a stove, and when...Ch. 1 - hat difference is necessary for heat to flow...Ch. 1 - What is the value of FT for a sample of gas whose...
Ch. 1 - What is the value of FP for a sample of gas whose...Ch. 1 - Prob. 1.12ECh. 1 - Hydrogen gas is used in weather balloon because it...Ch. 1 - Prob. 1.14ECh. 1 - A 2.0 L soda bottle is pressurized with 4.5 atm of...Ch. 1 - The Mount Pinatubo volcano eruption in 1991...Ch. 1 - Prob. 1.17ECh. 1 - Scottish physicist W. J. M. Rankine proposed an...Ch. 1 - Use the two appropriate values of R to determine a...Ch. 1 - Prob. 1.20ECh. 1 - Pressures of gases in mixtures are referred to as...Ch. 1 - Earths atmosphere is approximately 80 N2 and 20...Ch. 1 - The atmospheric surface pressure on Venus is 90...Ch. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - In the anaerobic oxidation of glucose by yeast,...Ch. 1 - What are the slopes of the following lines at the...Ch. 1 - For the following function, evaluate the...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Prob. 1.33ECh. 1 - Prob. 1.34ECh. 1 - What properties of a nonideal gas do the Vander...Ch. 1 - Prob. 1.36ECh. 1 - Prob. 1.37ECh. 1 - Calculate the Boyle temperatures for carbon...Ch. 1 - Prob. 1.39ECh. 1 - Prob. 1.40ECh. 1 - Table 1.4 show that the second virial coefficient...Ch. 1 - Prob. 1.42ECh. 1 - What is the van der Waals constant a for Ne in...Ch. 1 - Prob. 1.44ECh. 1 - Under what conditions would the van der Waals...Ch. 1 - By definition, the compressibility of an ideal gas...Ch. 1 - The second virial coefficient B and the third...Ch. 1 - Use the approximation 1 x-1 1 x x2 to...Ch. 1 - Why is nitrogen a good choice for the study of...Ch. 1 - Evaluate for a gas following the Redlich-Kwong...Ch. 1 - Numerically evaluate for one mole of methane...Ch. 1 - Under what conditions of volume does a van der...Ch. 1 - At high temperatures, one of the van der Waals...Ch. 1 - Under what conditions of temperature does a...Ch. 1 - The Berthelot equation of state for one mole of...Ch. 1 - Prob. 1.56ECh. 1 - Referring to exercises 1.6 and 1.7, does it matter...Ch. 1 - Prob. 1.58ECh. 1 - Use Figure 1.11 to construct the cyclic rule...Ch. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Calculate for one mole of an ideal gas at STP and...Ch. 1 - Prob. 1.63ECh. 1 - Show that = T/p for an ideal gas.Ch. 1 - Determine an expression for V/T p, n in terms of ...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Perform a units analysis on the exponent of the...Ch. 1 - Using the barometric formula, calculate the...Ch. 1 - The barometric formula can also be used for...Ch. 1 - Prob. 1.71ECh. 1 - Prob. 1.72ECh. 1 - Prob. 1.73ECh. 1 - Prob. 1.74ECh. 1 - Prob. 1.75ECh. 1 - Prob. 1.76ECh. 1 - Prob. 1.77ECh. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Use the ideal gas law to symbolically prove the...Ch. 1 - Prob. 1.81E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Under what conditions would the van der Waals constant b be negative? Do you think there are any gases for which this occurs?arrow_forwardUnder what conditions does the behavior of a real gas begin to differ significantly from the ideal gas law?arrow_forwardIf the initial temperature of an ideal gas at 2.250 bar2.250 bar is 62.00 ∘C62.00 ∘C , what final temperature would cause the pressure to be reduced to 1.550 bar1.550 bar ?arrow_forward
- Assuming that two gases have essentially the same van der Waals parameter b, but parameter a for gas 1 is much larger than for gas 2. Two identical containers contain 1 mole of gas 1 or 1 mole of gas 2 with the same temperature. Pressure in container with which gas will be higher?arrow_forwardDetermine the number of degrees of freedom (trans + rot) for each of the following gases; Ne, CO2, H2O. Then calculate the average total kinetic energy (per mole) at 25 celsius for each gasarrow_forwardA perfect gas undergoes isothermal compression, which reduces its volume by 2.20 dm3. The final pressure and volume of the gas are 5.04 barand 4.65 dm3, respectively. Calculate the original pressure of the gas in (i) bar,(ii) atm.arrow_forward
- Suppose the Ideal Gas Law is p=(nRT^2)/(V^2). Evaluate these derivatives: a. ((∂p/∂T))n,V b. ((∂p/∂V))n,T c. (∂/∂V(∂p/∂T))narrow_forward(a) List two experimental conditions under which gases deviatefrom ideal behavior. (b) List two reasons why the gasesdeviate from ideal behavior.arrow_forwardA spherical-shaped balloon 18 meters in diameter is filled with helium to a pressure of 108 kPa, 28 °C. It is to be used to transport military supplies on inaccessible forest. How many tons of supplies can be carried by the balloon?arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
DISTINCTION BETWEEN ADSORPTION AND ABSORPTION; Author: 7activestudio;https://www.youtube.com/watch?v=vbWRuSk-BhE;License: Standard YouTube License, CC-BY
Difference Between Absorption and Adsorption - Surface Chemistry - Chemistry Class 11; Author: Ekeeda;https://www.youtube.com/watch?v=e7Ql2ZElgc0;License: Standard Youtube License