Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 1, Problem 1.46E
By definition, the compressibility of an ideal gas is 1. By approximately what percentage does this change for hydrogen upon inclusion of the second virial coefficient term? How about for water vapor? Give the conditions under which you make this estimate.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Standard conditions are based on relevant environmentalconditions. If normal average surface temperature and pressureon Venus are 730. K and 90 atm, respectively, what is the stan-dard molar volume of an ideal gas on Venus?
Standard conditions are based on relevant environmental conditions. If normal average surface temperature and pressure on Venus are 730. K and 90 atm, respectively, what is the standard molar volume of an ideal gas on Venus?
Calculate the molar volume of carbon dioxide at 400K and 30 atm, given that the second Curial coefficient (B) of CO2 is -0.0605 L mol^-1. Compare your result with that obtained using the ideal-gas equation.
Chapter 1 Solutions
Physical Chemistry
Ch. 1 - A bomb calorimeter is a study metal vessel in...Ch. 1 - Difference between the system and the...Ch. 1 - Prob. 1.3ECh. 1 - Prob. 1.4ECh. 1 - Prob. 1.5ECh. 1 - Prob. 1.6ECh. 1 - Prob. 1.7ECh. 1 - A pot of cold water is heated on a stove, and when...Ch. 1 - hat difference is necessary for heat to flow...Ch. 1 - What is the value of FT for a sample of gas whose...
Ch. 1 - What is the value of FP for a sample of gas whose...Ch. 1 - Prob. 1.12ECh. 1 - Hydrogen gas is used in weather balloon because it...Ch. 1 - Prob. 1.14ECh. 1 - A 2.0 L soda bottle is pressurized with 4.5 atm of...Ch. 1 - The Mount Pinatubo volcano eruption in 1991...Ch. 1 - Prob. 1.17ECh. 1 - Scottish physicist W. J. M. Rankine proposed an...Ch. 1 - Use the two appropriate values of R to determine a...Ch. 1 - Prob. 1.20ECh. 1 - Pressures of gases in mixtures are referred to as...Ch. 1 - Earths atmosphere is approximately 80 N2 and 20...Ch. 1 - The atmospheric surface pressure on Venus is 90...Ch. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - In the anaerobic oxidation of glucose by yeast,...Ch. 1 - What are the slopes of the following lines at the...Ch. 1 - For the following function, evaluate the...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Prob. 1.33ECh. 1 - Prob. 1.34ECh. 1 - What properties of a nonideal gas do the Vander...Ch. 1 - Prob. 1.36ECh. 1 - Prob. 1.37ECh. 1 - Calculate the Boyle temperatures for carbon...Ch. 1 - Prob. 1.39ECh. 1 - Prob. 1.40ECh. 1 - Table 1.4 show that the second virial coefficient...Ch. 1 - Prob. 1.42ECh. 1 - What is the van der Waals constant a for Ne in...Ch. 1 - Prob. 1.44ECh. 1 - Under what conditions would the van der Waals...Ch. 1 - By definition, the compressibility of an ideal gas...Ch. 1 - The second virial coefficient B and the third...Ch. 1 - Use the approximation 1 x-1 1 x x2 to...Ch. 1 - Why is nitrogen a good choice for the study of...Ch. 1 - Evaluate for a gas following the Redlich-Kwong...Ch. 1 - Numerically evaluate for one mole of methane...Ch. 1 - Under what conditions of volume does a van der...Ch. 1 - At high temperatures, one of the van der Waals...Ch. 1 - Under what conditions of temperature does a...Ch. 1 - The Berthelot equation of state for one mole of...Ch. 1 - Prob. 1.56ECh. 1 - Referring to exercises 1.6 and 1.7, does it matter...Ch. 1 - Prob. 1.58ECh. 1 - Use Figure 1.11 to construct the cyclic rule...Ch. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Calculate for one mole of an ideal gas at STP and...Ch. 1 - Prob. 1.63ECh. 1 - Show that = T/p for an ideal gas.Ch. 1 - Determine an expression for V/T p, n in terms of ...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Perform a units analysis on the exponent of the...Ch. 1 - Using the barometric formula, calculate the...Ch. 1 - The barometric formula can also be used for...Ch. 1 - Prob. 1.71ECh. 1 - Prob. 1.72ECh. 1 - Prob. 1.73ECh. 1 - Prob. 1.74ECh. 1 - Prob. 1.75ECh. 1 - Prob. 1.76ECh. 1 - Prob. 1.77ECh. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Use the ideal gas law to symbolically prove the...Ch. 1 - Prob. 1.81E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
Use the ideal gas law to symbolically prove the cyclic rule of partial derivatives.
arrow_forward
Perform a units analysis on the exponent of the barometric function and verify that the overall exponent is unitless.
arrow_forward
What must the pressure be if the mean free path of Kr is 1.00cm? Assume d=185pm and T=25.0C.
arrow_forward
Repeat the previous exercise for a gas that follows the Berthelot equation of state see exercise 1.55.
arrow_forward
Determine the expressions for the following, assuming that the ideal gas law holds.
arrow_forward
Under what conditions of volume does a van der Waals gas behave like an ideal gas? Use the van der Waals equation of state to justify your answer.
arrow_forward
Evaluate for a gas following the Redlich-Kwong equation of state? pV
arrow_forward
The atmospheric surface pressure on Venus is 90 bar and is composed of 96 carbon dioxide and approximately 4 various other gases. Given a surface temperature of 730 K, what is the mass of carbon dioxide present per cubic centimeter at the surface?
arrow_forward
Use the ideal gas law to demonstrate the cyclic rule of partial derivatives.
arrow_forward
Under what conditions of temperature does a Redlich-Kwong gas behave like an ideal gas? Use the Redlich-Kwong equation of state to justify your answer.
arrow_forward
Derive the reduced expression for the compressibility factor z of a real gas; Explain in detail how the volume of the real gas at a given temperature and pressure can be determined using this mathematical expression and an appropriate graph.
arrow_forward
intracorroding molar mass and density of ideal gases
arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY