Organic Chemistry - MasteringChemistry
7th Edition
ISBN: 9780321867148
Author: Bruice
Publisher: PEARSON
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Chapter 1, Problem 50P
Predict the approximate bond angles:
- a. the C—N—H bond angle in (CH3)2NH2
- b. the C—O—H bond angle in CH3OH
- c. the C—N—H bond angle in (CH3)2NH
- d. the C—N—C bond angle in (CH3)2NH
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Chapter 1 Solutions
Organic Chemistry - MasteringChemistry
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 3PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - Explain why HCL has a smaller dipole moment than...
Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 15PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 19PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 21PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 23PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 32PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 35PCh. 1.14 - Prob. 36PCh. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - Prob. 41PCh. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - What of the following molecules would you expect...Ch. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 51PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - 53. What is the hybridization of each of the...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 68PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - Prob. 73P
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- A. H2NC(O)H (oxygen and the single hydrogen are both bonded to C) Step 1. Draw the lewis structure Step 2. Description of shape: Central Atom 1= ___ Electron groups = ___ ____ non bonding= ____ total Central Atom 2= ___ Electron groups = ___ ____ non bonding= ____ total Electron group arrangement for central atom 1: Electron group arrangement for central atom 2: Geometry (shape) around central atom 1: Geometry (shape) around central atom 2: Step 3: List and Name all bond angles and give the degree.arrow_forwardTrue or false The F – N – F bond angle in NF3 is smaller than the H – N – H bond angle in NH3.arrow_forwardYou come across a bottle in the stock room labeled CHCl3 a.Draw the Lewis dot structure of the molecule b.Identify the molecular geometry of the molecule c.dentify if the molecule is polar or non-polar. d.Do you expect this molecule to interact more with water (H2O) or methane (CH4)?Explain why.arrow_forward
- A. HC(O)OH (both oxygens are bonded to C) Step 1. Draw the lewis structure Step 2. Description of shape: Central Atom 1= ___ Electron groups = ___ ____ non bonding= ____ total Central Atom 2= ___ Electron groups = ___ ____ non bonding= ____ total Electron group arrangement for central atom 1: Electron group arrangement for central atom 2: Geometry (shape) around central atom 1: Geometry (shape) around central atom 2: Step 3: List and Name all bond angles and give the degree.arrow_forwardChange ethane into 1,2-ethanediol (HOCH2CH2OH) by removing one hydrogen atom from each carbon atom and replacing with a hydroxide (-OH) group. Build a model of the 1,2-ethanediol molecule. A. Identify the electron-pair and molecular geometry around each carbon and oxygen atom. B. What are the bond angles for H-C-H? For H-C-C? For C-C-O? For C-O-H? C. Draw two different structures of the molecule in which the –OH groups on the two carbon atoms have different orientations with respect to each other.arrow_forwardDraw the Lewis structure for HCN.a.What is the electron domain geometry of C?b.What is the molecular geometry of C?c.What is the approximate bond angle of the H-C-N?d.Is this molecule polar?arrow_forward
- Predict the approximate bond angles for a. the C¬N¬C bond angle in (CH3)2N + H2. b. the C¬N¬H bond angle in CH3CH2NH2. c. the H¬C¬N bond angle in (CH3)2NH. d. the H¬C¬O bond angle in CH3OCH3.arrow_forwarda) Compare and contrast the three-dimensional structure of methane CH4 and ammonia NH3. b) How are the angles in these molecules different? c) Explain why these bond angles are not the samearrow_forwardWhich statement A-D about VSEPR theory is not correct? Select one: a. The steric number has five values from 2 to 6. b. Statements A-D are all correct. c. In VSEPR theory, the shape or geometry of a molecule is determined by electron-electron repulsion. d. The steric number of a central atom is the sum of the number of bonds and lone pairs around the atom. e. The molecular shape or geometry can differ from the electron-pair geometry.arrow_forward
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