Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition
8th Edition
ISBN: 9780134473178
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 1, Problem 53P
Predict the approximate bond angles:
- a. the C—N—H bond angle in (CH3)2NH2
- b. the C—O—H bond angle in CH3OH
- c. the C—N—H bond angle in (CH3)2NH
- d. the C—N—C bond angle in (CH3)2NH
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Chapter 1 Solutions
Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
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- A. H2NC(O)H (oxygen and the single hydrogen are both bonded to C) Step 1. Draw the lewis structure Step 2. Description of shape: Central Atom 1= ___ Electron groups = ___ ____ non bonding= ____ total Central Atom 2= ___ Electron groups = ___ ____ non bonding= ____ total Electron group arrangement for central atom 1: Electron group arrangement for central atom 2: Geometry (shape) around central atom 1: Geometry (shape) around central atom 2: Step 3: List and Name all bond angles and give the degree.arrow_forwardTrue or false The F – N – F bond angle in NF3 is smaller than the H – N – H bond angle in NH3.arrow_forwardYou come across a bottle in the stock room labeled CHCl3 a.Draw the Lewis dot structure of the molecule b.Identify the molecular geometry of the molecule c.dentify if the molecule is polar or non-polar. d.Do you expect this molecule to interact more with water (H2O) or methane (CH4)?Explain why.arrow_forward
- A. HC(O)OH (both oxygens are bonded to C) Step 1. Draw the lewis structure Step 2. Description of shape: Central Atom 1= ___ Electron groups = ___ ____ non bonding= ____ total Central Atom 2= ___ Electron groups = ___ ____ non bonding= ____ total Electron group arrangement for central atom 1: Electron group arrangement for central atom 2: Geometry (shape) around central atom 1: Geometry (shape) around central atom 2: Step 3: List and Name all bond angles and give the degree.arrow_forwardChange ethane into 1,2-ethanediol (HOCH2CH2OH) by removing one hydrogen atom from each carbon atom and replacing with a hydroxide (-OH) group. Build a model of the 1,2-ethanediol molecule. A. Identify the electron-pair and molecular geometry around each carbon and oxygen atom. B. What are the bond angles for H-C-H? For H-C-C? For C-C-O? For C-O-H? C. Draw two different structures of the molecule in which the –OH groups on the two carbon atoms have different orientations with respect to each other.arrow_forwardDraw the Lewis structure for HCN.a.What is the electron domain geometry of C?b.What is the molecular geometry of C?c.What is the approximate bond angle of the H-C-N?d.Is this molecule polar?arrow_forward
- Predict the approximate bond angles for a. the C¬N¬C bond angle in (CH3)2N + H2. b. the C¬N¬H bond angle in CH3CH2NH2. c. the H¬C¬N bond angle in (CH3)2NH. d. the H¬C¬O bond angle in CH3OCH3.arrow_forwarda) Compare and contrast the three-dimensional structure of methane CH4 and ammonia NH3. b) How are the angles in these molecules different? c) Explain why these bond angles are not the samearrow_forwardWhich statement A-D about VSEPR theory is not correct? Select one: a. The steric number has five values from 2 to 6. b. Statements A-D are all correct. c. In VSEPR theory, the shape or geometry of a molecule is determined by electron-electron repulsion. d. The steric number of a central atom is the sum of the number of bonds and lone pairs around the atom. e. The molecular shape or geometry can differ from the electron-pair geometry.arrow_forward
- The H – C – H bond angle is greater than the Cl – C – Cl bond angle in CH2Cl2.arrow_forwardMolecular Geometry Directions: Show the expanded structure (draw all the bonds and lone pairs) of C15H11I4NO4 (Levothyroxine). Determine the molecular geometry of each central atom. Color each central atom based on its molecular geometry and include a key for your colors. For example, color tetrahedral C’s red, trigonal planar C’s , blue, etc. Thank you!arrow_forward1. (A) Provide an example for each of the following: (a) a molecule that only has dispersion forces as IMFs (b) a molecule that has dispersion and dipolar IMFs (c) a molecule that can experience hydrogen bonding (B) Why does NH3 have a higher boiling point than BH3? To answer this question, draw out the Lewis structure for each molecule, and then draw out the VSEPR shape for each molecule.arrow_forward
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