Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 1, Problem 55P
Boron is a group IIIA element. Open the molecular model for boron trifluoride from the 3D Molecular Models section of the book’s website. Near the boron atom, above and below the plane of the atoms in
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2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew.
b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.
Write orbital diagrams (boxes with arrows in them) to represent the electron configurations of carbon before and after sp hybridization.
1,Which of the following statements is true?
Group of answer choices
A, A p bond results from the sideways overlap of hybridized orbitals.
B, A p bond is the result of the overlap of an s orbital and a p orbital.
C, A p bond is twice as strong as a sigma bond.
D, A p bond results from the sideways overlap of p orbitals.
2, According to Lewis structure for the simplest amino acid, glycine, H2NCH2CO2H (check EXAMPLE 4.16) and valence-bond theory, the bonding is described as following:Group of answer choices
A, 8σ, 1π
B, 14σ, 1π
C, 9σ, 1π
D, 10σ, 0π
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1PPCh. 1 - Prob. 2PPCh. 1 - Prob. 3PPCh. 1 - Prob. 4PPCh. 1 - Prob. 5PPCh. 1 - Prob. 6PPCh. 1 - Prob. 7PPCh. 1 - Prob. 8PPCh. 1 - Prob. 9PPCh. 1 - Prob. 10PP
Ch. 1 - Prob. 11PPCh. 1 - Prob. 12PPCh. 1 - Prob. 13PPCh. 1 - Prob. 14PPCh. 1 - Prob. 15PPCh. 1 - Prob. 16PPCh. 1 - Prob. 17PPCh. 1 - Prob. 18PPCh. 1 - Prob. 19PPCh. 1 - Prob. 20PPCh. 1 - Prob. 21PPCh. 1 - Practice Problem 1.22 Which of the following...Ch. 1 - Prob. 23PPCh. 1 - Prob. 24PPCh. 1 - Practice Problem 1.25
What do the bond angles of...Ch. 1 - Prob. 26PPCh. 1 - Practice Problem 1.27
Use VSEPR theory to predict...Ch. 1 - Practice Problem 1.28 Predict the bond angles of...Ch. 1 - 1.29 Which of the following ions possess the...Ch. 1 - 1.30 Write a Lewis structure for each of the...Ch. 1 - Prob. 31PCh. 1 - Add any unshared electrons to give each element an...Ch. 1 - Prob. 33PCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - 1.37 Write bond-line formulas for all of the...Ch. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - (a) Cyanic acid (HOCN) and isocyanic acid (HN=C=O)...Ch. 1 - Consider a chemical species (either a molecule or...Ch. 1 - 1.44 Consider a chemical species like the one in...Ch. 1 - 1.45 Consider another chemical species like the...Ch. 1 - Draw a three-dimensional orbital representation...Ch. 1 - Ozone (O3) is found in the upper atmosphere where...Ch. 1 - Write resonance structures for the azide ion, N3....Ch. 1 - Write structural formulas of the type indicated:...Ch. 1 - Prob. 50PCh. 1 - 1.51 In Chapter 15 we shall learn how the...Ch. 1 - Prob. 52PCh. 1 - (a) Consider a carbon atom in its ground state....Ch. 1 - Open computer molecular models for dimethyl ether,...Ch. 1 - Boron is a group IIIA element. Open the molecular...Ch. 1 - 1.56 There are two contributing resonance...Ch. 1 - Prob. 1LGPCh. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Prob. 7LGPCh. 1 - Prob. 8LGP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw orbital diagrams (boxes with arrows in them) to represent the electron configurations of carbon before and after sp hybridization.arrow_forwardWhen selecting a ball from your model kit to serve as the phosphorous atom from above, how many holes should the ball have? Why? What is the molecular geometry around the central atom in CO2? What is the hybridization on the central carbon atom in CCl2F2?arrow_forward1. a) Draw the dominant Lewis structure for the allene molecule (1,2-propyl diene, CH2CCH2 ) and use VSEPR theory to determine the molecule's geometry. In specifying the geometry give all bond angles and specify which nuclei lie in the same plane. b) Propose a hybridization and bonding scheme for the atoms in allene. That is, specify how each of the atoms is hybridized, which atomic orbitals overlap to form bonding molecular orbitals, and the nature (i.e., 0", 7f, etc.) of these molecular orbitals. c) Draw a plausible valence molecular orbital level diagram for allene (include only bonding MOs) based on the results from (b). d) Based on the work from (c) deduce the valence electronic configuration of the ground state of allene. e) Is the molecule planar or nonplanar? Explain your answerarrow_forward
- 1. a) Draw the dominant Lewis structure for the allene molecule (1,2-propyl diene, CH2CCH2 ) and use VSEPR theory to determine the molecule's geometry. In specifying the geometry give all bond angles and specify which nuclei lie in the same plane. b) Propose a hybridization and bonding scheme for the atoms in allene. That is, specify how each of the atoms is hybridized, which atomic orbitals overlap to form bonding molecular orbitals, and the nature (i.e., sigma", pi, etc.) of these molecular orbitals. c) Draw a plausible valence molecular orbital level diagram for allene (include only bonding MOs) based on the results from (b). d) Based on the work from (c) deduce the valence electronic configuration of the ground state of allene. e) Is the molecule planar or nonplanar? Explain your answer Answer subparts c, d, and earrow_forwardDraw the Lewis structure for CH4O . Is the molecule polar or nonpolar? What is the electronic geometry(around O), molecular geometry(around O), and hybridization of oxygen? Lastly, draw the 3-D structure of the entire molecule.arrow_forward4. Answer the following questions about the molecules SbF5^2-.a. Draw the Lewis structure.b. Write the valence shell electron configuration for Sb^2-.c. Draw the valence orbital diagram for Sb^2-.d. Draw the hybridized orbital diagram for Sb^2-.e. Give a bond description for each bond in the molecule.arrow_forward
- For the following descriptions of molecules, draw the Lewis structure (showing all atoms, lone pairs, formal changes) of the molecule and show all bond angles (assuming ideal VSEPR angles) 2) An organic compound with molecular formula H2CNO+. Both C and O are sp hybridized while N is sp3 hybridized.arrow_forward1. How many sp^3 orbitals does your oxygen have? * 2. How many Pi bond/s connect/s your Oxygen to your Carbon? * 3. How many sigma bond/s connect/s your Oxygen to your Carbon? * 4. Which line representation would tell the viewer of which hydrogen is toward him/her (closest to the viewer)? *A. AB. BC. CD. None of the above 5. What hybrid orbital do all your central atoms have? *A. spB. sp^2C. sp^3D. spd^3 6. If we are to consider only your C-O-C, what geometry will they form? *A. tetrahedralB. trigonal pyramidalC. trigonal planarD. linearE. bent 7. What angle will be closest to the angle of number 1? *A. 180B. 109.5C. 120D. 90 8. What angle will be closest to the angle of number 2? *A. 180B. 109.5C. 120D. 90 9. How many hybrid orbitals that formed covalent bonds can you count? *1 pointA. 6B. 7C. 8D. 9E. 10F. 11 10. How many atoms were bonded covalently? *arrow_forwardWhich is the correct electron configuration for B2+ according to the molecular orbital theory? (5B) A. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz2 B. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1 C. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz1 D. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1π2py1arrow_forward
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