Chemistry: The Central Science, Books a la Carte Edition (13th Edition)
Chemistry: The Central Science, Books a la Carte Edition (13th Edition)
13th Edition
ISBN: 9780321934208
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 1, Problem 57E
Interpretation Introduction

Interpretation:

The facts related to the resonance stabilization of benzene, heat of hydrogenation and fuel value of benzene and acetylene are to be determined; also the experiment to prove the existence of resonance in cyclooctatetraene is to be determined.

Concept Introduction:

The enthalpy change of the combustion reaction is calculated by the difference of sum of the enthalpy change of products and reactants.

(a)

To determine:

The comparison of heat of hydrogenation of benzene and acetylene and the greater fuel value out of 1.0mol benzene and 3.0mol acetylene; also the explanation of stability of benzene on the basis of these calculations.

Interpretation Introduction

Step 1:

To determine:

The heat of hydrogenation and fuel value of 3.0mol acetylene.

Interpretation Introduction

Step 2:

To determine:

The heat of hydrogenation and fuel value of 1.0mol benzene.

Interpretation Introduction

(b)

To determine:

The heat of hydrogenation and fuel value of toluene.

Interpretation Introduction

(c)

To determine:

The explanation of stabilization of benzene by using the given values of heat of hydrogenation.

Interpretation Introduction

(d)

To determine:

The explanation of resonance and stability of benzene on the basis of bond lengths and bond angles.

Interpretation Introduction

(e)

To determine:

The experiment to prove the existence of resonance in cyclo octatetraene.

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Chapter 1 Solutions

Chemistry: The Central Science, Books a la Carte Edition (13th Edition)

Ch. 1.6 - Practice Exercise 2 By using a conversion factor...Ch. 1.6 - Practice Exercise 1 Fabiola, who lives in Mexico...Ch. 1.6 - Prob. 1.7.1PECh. 1.6 - Practice Exercise 2 A car travels 28 mi per gallon...Ch. 1.6 - Practice Exercise 2 The surface area of Earth is...Ch. 1.6 - Practice Exercise 1 Composite decking is a...Ch. 1.6 - Prob. 1.9.1PECh. 1.6 - Practice Exercise 2 If the mass of the container...Ch. 1.6 - Practice Exercise 1 Which of the following is the...Ch. 1.6 - Aspirin is composed of 60.0% carbon, 4.5%...Ch. 1.6 - Practice Exercise 1 Which of the following weights...Ch. 1.6 - Practice Exercise 2 How many picometers are there...Ch. 1.6 - Practice Exercise 1 Using Wolfram Alpha...Ch. 1.6 - Practice Exercise 2 Ethylene glycol, the major...Ch. 1.6 - Prob. 1.13.1PECh. 1.6 - Practice Exercise 2 Calculate the density of a...Ch. 1 - The reaction between reactant A (blue spheres) and...Ch. 1 - Prob. 2ECh. 1 - Describe the separation method(s) involved in...Ch. 1 - Prob. 4ECh. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - Prob. 7ECh. 1 - 2447 What are the molecular and empirical formulas...Ch. 1 - When you convert units, how do you decide which...Ch. 1 - Prob. 10ECh. 1 - 2-60 The most common charge associated with...Ch. 1 - Prob. 12ECh. 1 - 2.84 Consider the following organic substances:...Ch. 1 - 2.96 Gallium (Ga) consists of two naturally...Ch. 1 - 2.108 Cyclopropane is an interesting hydrocarbon....Ch. 1 - Write a balanced equation for (a) solid...Ch. 1 - Calculate the molar mass of Ca(NO3)2Ch. 1 - Prob. 18ECh. 1 - Imagine you are working on ways to improve the...Ch. 1 - A key step in balancing chemical equations is...Ch. 1 - a. The characteristic odor of pineapple is due to...Ch. 1 - The complete combustion of octane, Cngs, a...Ch. 1 - Prob. 23ECh. 1 - Prob. 24ECh. 1 - 4.53 Write balanced molecular and net ionic...Ch. 1 - Prob. 26ECh. 1 - Prob. 27ECh. 1 - Prob. 28ECh. 1 - 4.101 Hard water contains Ca2+ , Mg2 + , and Fe2+...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Prob. 32ECh. 1 - Imagine that you are climbing a mountain. Is the...Ch. 1 - A gas is confined to a cylinder under constant...Ch. 1 - 5.100 An aluminum can of a soft drink is placed...Ch. 1 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 1 - The precipitation reaction between AgNO3(aq) and...Ch. 1 - Consider the following three moving objects: a...Ch. 1 - The speed of sound in dry air at 20°C is 343 m/s...Ch. 1 - Prob. 40ECh. 1 - Calculate the energy of a photon of...Ch. 1 - Using Heisenberg's uncertainty principle,...Ch. 1 - Prob. 43ECh. 1 - The following do not represent valid ground-state...Ch. 1 - Prob. 45ECh. 1 - Prob. 46ECh. 1 - Arrange the following atoms and ions in order of...Ch. 1 - Prob. 48ECh. 1 - Prob. 49ECh. 1 - The distance from Grand Rapids, Michigan, to...Ch. 1 - Prob. 51ECh. 1 - Prob. 52ECh. 1 - Prob. 53ECh. 1 - Prob. 54ECh. 1 - Prob. 55ECh. 1 - Which of the these molecules has a Lewis structure...Ch. 1 - Prob. 57ECh. 1 - Write the electron configuration for the element...Ch. 1 - (a) Classify each of the following as a pure...Ch. 1 - Prob. 60AECh. 1 - Prob. 61AECh. 1 - Prob. 62AECh. 1 - Prob. 63AECh. 1 - Prob. 64AECh. 1 - Prob. 65AECh. 1 - Prob. 66AECh. 1 - Prob. 67AECh. 1 - Prob. 68AECh. 1 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 1 - Prob. 70AECh. 1 - The iodine bromide molecule, IBr, is an...Ch. 1 - Prob. 72AECh. 1 - Prob. 73AECh. 1 - Prob. 74AECh. 1 - Prob. 75AECh. 1 - Prob. 76AECh. 1 - Prob. 77AECh. 1 - 10.12 The graph below shows the change in...Ch. 1 - Prob. 79AECh. 1 - Prob. 80AECh. 1 - Prob. 81AECh. 1 - Prob. 82AECh. 1 - Prob. 83AECh. 1 - Prob. 84AECh. 1 - Prob. 85AECh. 1 - Prob. 86AECh. 1 - Prob. 87AECh. 1 - Prob. 88AE
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