Connect Online Access 1-Semester for Organic Chemistry
6th Edition
ISBN: 9781260475609
Author: SMITH, Janice
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 1, Problem 72P
Two useful organic compounds that contain
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Two useful organic compounds that contain Cl atoms are vinyl chloride (CH2=CHCl) and chloroethane (CH3CH2Cl). Vinyl chloride is the starting material used to prepare poly(vinyl chloride), a plastic in insulation, pipes, and bottles. Chloroethane (ethyl chloride) is a local anesthetic. Why is the C–Cl bond in vinyl chloride stronger than the C–Cl bond in chloroethane?
Two useful organic compounds that contain Cl atoms are vinyl chloride(CH2=CHCl) and chloroethane (CH3CH2Cl). Vinyl chloride is the startingmaterial used to prepare poly(vinyl chloride), a plastic in insulation,pipes, and bottles. Chloroethane (ethyl chloride) is a local anesthetic.Why is the C–Cl bond in vinyl chloride stronger than the C–Cl bond inchloroethane?
Two useful organic compounds that contain Cl atoms are vinyl chloride (CH2 = CHCl) and chloroethane (CH3CH2Cl). Vinyl chloride is the starting material used to prepare poly(vinyl chloride), a plastic used in insulation, pipes, and bottles. Chloroethane (ethyl chloride) is a tica roman local anesthetic. Why is the C–Cl bond of vinyl chloride stronger than the C–Cl bond in chloroethane ?
Chapter 1 Solutions
Connect Online Access 1-Semester for Organic Chemistry
Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9PCh. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12PCh. 1.6 - Prob. 13PCh. 1.6 - Prob. 14PCh. 1.6 - Prob. 16P
Ch. 1.6 - Prob. 17PCh. 1.7 - Prob. 18PCh. 1.7 - Prob. 19PCh. 1.7 - Using the principles of VSEPR theory, you can...Ch. 1.8 - Convert each condensed formula to a Lewis...Ch. 1.8 - Prob. 22PCh. 1.8 - Prob. 23PCh. 1.8 - Convert each skeletal structure to a complete...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Assign formal charges to each and atom in the...Ch. 1 - Prob. 44PCh. 1 - Prob. 46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Consider compounds A-D, which contain both a...Ch. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - 1.61 Convert each molecule into a skeletal...Ch. 1 - Prob. 65PCh. 1 - Predict the hybridization and geometry around each...Ch. 1 - Prob. 68PCh. 1 - Ketene, , is an unusual organic molecule that has...Ch. 1 - Rank the following bonds in order of increasing...Ch. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Prob. 74PCh. 1 - Anacin is an over-the-counter pain reliever that...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Prob. 85PCh. 1 - Prob. 86PCh. 1 - Prob. 87PCh. 1 - Prob. 88P
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- Two compounds have the molecular formula N3H3. One of the compounds, triazene, contains an NN bond; the other compound, triaziridene, does not. (a) Write the correct Lewis structures for each compound. (b) Approximate the bond angle between the three nitrogen atoms in each compound.arrow_forwardTwo useful organic compounds that contain Cl atoms are vinyl chloride (CH2 = CHCl) and chloroethane (CH3CH2Cl). Vinyl chloride is the starting material used to prepare poly(vinyl chloride), a plastic used in insulation, pipes, and bottles.Chloroethane (ethyl chloride) is a tica roman local anesthetic. Why is the C–Cl bond of vinyl chloride stronger than the C–Cl bond in chloroethane ?arrow_forwardWhich of the following bonds is most polar: S¬Cl, S¬Br, Se¬Cl,or Se¬Br?arrow_forward
- The average bond energy (enthalpy) for a C=C double bond is 614 kJ/molkJ/mol and that of a C−C single bond is 348 kJ/molkJ/mol. If it takes 4.42×10−19 J/molecule to break the C=C double bond. What is the longest wavelength λ of light that will provide photons of sufficient energy to break the π bond and cause the isomerization? Express your answer numerically in nanometers.arrow_forwardCarbon-carbon bonds form the “backbone” of nearly every organic and biological molecule. The average bond energy of the C¬C bond is 347 kJ/mol. Calculate the frequency and wavelength of the least energetic photon that can break an average C¬C bond. In what region of the electromagnetic spectrum is this radiation?arrow_forwardFormation of ammonia from nitrogen and hydrogen is an exothermic process. Which of the following statements is true about the bonds that are broken and formed during this reaction? N2(g) + 3H2(g) ---> 2NH3(g) a.) products have lower PE because product bonds are weaker than reactants b.) products have higher PE because product bonds are stronger than reactants c.) products have higher PE because product bonds are weaker than reactants d.) products have lower PE because product bonds are stronger than reactantsarrow_forward
- 5. The reason there is danger in exposure to high-energy radiation (e.g., ultraviolet and X rays) is that the radiation can rupture chemical bonds. In some cases, cancer can be caused it. A carbon-carbon single bond has a bond energy of approximately 348 kJ per mole. What wavelength of light is required to provide sufficient energy to break the C-C bond? In which region of the electromagnetic spectrum is this wavelength located?arrow_forwardDefine Compounds Containing C–Z σ Bonds ?arrow_forwardBased on the results of the solubility tests and chemical tests, what is the most probable structure of C4H8? Draw the compound using line-bond formula or lewis structure.arrow_forward
- In addition to CO, CO2, and C3O2, there is another molecular oxide of carbon, pentacarbon dioxide, C5O2, a yellow solid. (a) What is the approximate C-to-C-to-O bond angle in pentacarbon dioxide? (b) What is the approximate C-to-C-to-C bond angle in this compound?arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardThe hyponitrite ion, ONNO, exists in solid compounds as the trans isomer. Using valence bond theory, explain why cistrans isomers might be expected for this ion. Draw structural formulas of the cistrans isomers.arrow_forward
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