Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 10, Problem 10.21P
10-21 Explain how to use the valence-shell electron-pair repulsion (VSEPR) model to predict bond angles and geometry about atoms of carbon, oxygen, and nitrogen.
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Chapter 10 Solutions
Introduction to General, Organic and Biochemistry
Ch. 10.3 - Prob. 10.1PCh. 10.4 - Prob. 10.2PCh. 10.4 - Prob. 10.3PCh. 10.4 - Prob. 10.4PCh. 10.4 - Prob. 10.5PCh. 10.4 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - 10-9 Is there any difference between vanillin made...Ch. 10 - Prob. 10.10P
Ch. 10 - 10-11 What important experiment did Wohler carry...Ch. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - 10-15 How many electrons are in the valence shell...Ch. 10 - 10-16 What is the relationship between the number...Ch. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - 10-19 Write Lewis structures for these ions. (a)...Ch. 10 - 10-20 Why are the following molecular formulas...Ch. 10 - 10-21 Explain how to use the valence-shell...Ch. 10 - 10-22 Suppose you forget to take into account the...Ch. 10 - Suppose you forget to take into account the...Ch. 10 - 10-24 Use the VSEPR model to predict the bond...Ch. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - 10-27 What is meant by the term functional group?Ch. 10 - 10-28 List three reasons why functional groups are...Ch. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - 10-32 Draw a structural formula for the one...Ch. 10 - 10-33 What is the meaning of the term tertiary (...Ch. 10 - Prob. 10.34PCh. 10 - Draw structural formulas for each of the...Ch. 10 - 10-36 Draw structural formulas for the six ketones...Ch. 10 - 10-37 Draw structural formulas for the eight...Ch. 10 - Prob. 10.38PCh. 10 - 10-39 (Chemical Connections 10A) How was Taxol...Ch. 10 - Prob. 10.40PCh. 10 - Prob. 10.41PCh. 10 - Silicon is immediately below carbon in Group 4A of...Ch. 10 - 10-43 Phosphorus is immediately below nitrogen in...Ch. 10 - Draw the structure for a compound with the...Ch. 10 - 10-45 Draw structural formulas for the eight...Ch. 10 - Prob. 10.46PCh. 10 - 10-47 Which of these covalent bonds are polar, and...Ch. 10 - Of the bonds in Problem 10-47, which is the most...Ch. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Following is a structural formula for naphthalene....Ch. 10 - Prob. 10.52PCh. 10 - Prob. 10.53PCh. 10 - Urea, (NH.,)2CO, is used in plastics and in fertil...Ch. 10 - Prob. 10.55PCh. 10 - Prob. 10.56PCh. 10 - Aspirin is prepared by the reaction of salicylic-...Ch. 10 - Following is the structural formula of acetamide....Ch. 10 - Prob. 10.59P
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- 10-43 Phosphorus is immediately below nitrogen in Group 5A of the Periodic Table. Predict the C—P—C bond angles in trimethylphosphine, (CHaJaP.arrow_forward10-24 Use the VSEPR model to predict the bond angles and geometry about each highlighted atom. (Hint-. Remember to take into account the presence of unshared pairs of electrons.) H H I I H-C-C-O-H I I H H H-C=C-C1 H Harrow_forwardSilicon is immediately below carbon in Group 4A of the Periodic Table. Predict the C—Si—C bond angles in tetramethylsilane, (CH3)4Si.arrow_forward
- Urea, (NH.,)2CO, is used in plastics and in fertil izers. It is also the primary nitrogen-containing substance excreted by humans. O I I H H Urea Complete the Lewis structure of urea, showing all valence electrons. Predict the bond angle about each C and N. Which is the most polar bond in the molecule? (d, Is urea polar or nonpolar?arrow_forward10-22 Suppose you forget to take into account the presence of the unshared pair of electrons on nitrogen in the molecule NH3. What would you then predict for the H—N—H bond angles and the geometry (bond angles and shape) of ammonia?arrow_forward10-16 What is the relationship between the number of electrons in the valence shell of each of the following atoms and the number of covalent bonds each forms? (a) Carbon(b) Oxygen (c) Nitrogen(d) Hydrogenarrow_forward
- 10-20 Why are the following molecular formulas impossible? (a) CH5 C2H7arrow_forward10-37 Draw structural formulas for the eight carboxylicacids with the molecular formula C6H12O2.arrow_forward10-19 Write Lewis structures for these ions. (a) HCOf(b) CO32- Bicarbonate ionCarbonate ion (c) ch3coo-(d)Cr Acetate ionChloride ionarrow_forward
- Following is the structural formula of acetamide. H O H — C—C— N— H I I H H Acetamide (an amide > Complete the Lewis structure for acetamide, showing all valence electrons. Use the valence-shell electron-pair repulsion (VSEPR) model (Section 3-10) to predict all bond angles in acetamide. Which is the most polar bond in acetamide?arrow_forward10-15 How many electrons are in the valence shell of each of the following atoms? Write a Lewis structure for an atom of each element. (Hint: Use the Periodic Table.) (a) Carbon(b) Oxygen (c) Nitrogen(d) Fluorinearrow_forward10-47 Which of these covalent bonds are polar, and whichare nonpolar? (Hint: Review Section 3-7B.) (a) C—C (b) C=C(c) C—H (d) C—O (e) O—H (f) C—N(g) N—H (h) N—Oarrow_forward
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